Salt-cake possesses certain other properties that make it somewhat
troublesome to deal with as a glass-making material. Thus, on prolonged
exposure, particularly to moist air, the powdered salt-cake absorbs
moisture from the atmosphere and undergoes partial conversion into the
crystalline form of “Glauber’s Salt,” a process which results in the
formation of exceedingly hard masses. Ground salt-cake, therefore,
cannot be stored for any length of time without incurring the necessity
of regrinding, and this accretive action even comes into play when
mixtures of glass-making materials, containing salt-cake as one
ingredient, are stored. In practice, therefore, salt-cake can only be
ground as it is wanted, and its physical properties make it difficult
to grind it at all fine, while the dust arising from this process is
peculiarly irritating, although not seriously injurious to health.
Potash is utilised in glass-making almost entirely in the form of
carbonate, generally called “pearl-ash.” Originally derived from the
ashes of wood and other land plants, this substance is now manufactured
by processes similar to those described in the case of soda, the raw
material being potassium chloride derived from natural deposits such
as those at Stassfurth. The pearl-ash thus commercially obtainable
is a fairly pure substance, but its use is complicated by the fact
that it is strongly hygroscopic and rapidly absorbs water from the
atmosphere. Where it is desired to produce potash glasses of constant
composition, frequent analytical determinations of the moisture
contents of the pearl-ash are necessary, and the composition of the
glass mixture requires adjustment in accordance with the results of
these determinations.
The alkalies are also introduced into glass in the form of nitrates
(potassium nitrate, or saltpetre, and sodium nitrate, or nitre); but
although these substances act as sources of alkali in the glass, they
are employed essentially for the sake of their oxygen contents. Such
oxidising agents are not, of course, added to glass mixtures containing
sulphates and carbon, but are employed to purify the mixtures
containing alkali carbonates, and more especially to oxidise the flint
glasses. Since these substances are only introduced into glass in small
quantities their extreme purity is not of such great importance to the
glass-maker, and the ordinary “refined” qualities of both nitrates are
found amply pure enough to answer the highest requirements.
Public-domain text, read in full here on John Shaqi.
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