A certain number of natural minerals which contain an appreciable
quantity of alkali are sometimes utilised as raw materials for
glass manufacture. The most important of these are the minerals of
the felspar class already referred to. These, however, contain a
considerable proportion of alumina, while all but the purest varieties
also contain more or less considerable quantities of iron. Some
glass-makers regard alumina as an undesirable constituent, while others
take the opposite view, and upon this view their use of felspathic
minerals will depend. For the cheaper varieties of glass, however,
such as bottle glass, felspathic minerals and rocks, such as granite
and basalt, are freely used as raw materials. Another mineral in which
both alkali and alumina are found is cryolite. This mineral is a
double fluoride of soda and alumina, whose properties are particularly
valuable in the production of opal and opalescent glasses. As a mere
source of alkali, however, cryolite is much too expensive.
(3) _Sources of Bases other than Alkalies._--The most important of
these are lime and lead oxide, the former being required for the
production of all varieties of plate and sheet-glass, as well as for
bottles and a large proportion of pressed and blown glass, while lead
is an essential ingredient of all flint glass. The only other base
having any considerable commercial importance in connection with
glass-making is barium oxide, while oxide of zinc, magnesia, and a
few other substances are used in the manufacture of special glasses
for scientific, optical or technical purposes, where glass of special
properties is required. The metallic oxides which are used for the
production of coloured glass are, of course, also basic bodies. These
will be treated in connection with coloured glasses, with the exception
of manganese dioxide, which is used in large quantities in the
manufacture of many ordinary “white” glasses.
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