_Calcium Oxide_ (lime) is generally introduced into glass mixtures
in the form of either the carbonate or the hydrated oxide (slaked
lime). The carbonate may be derived either from natural sources, or
it may be of chemical origin, while the hydrate is always obtained
by the calcination of the carbonate, followed by “slaking” the lime
thus produced. Natural calcium carbonate occurs in great quantities
in the form of chalk and limestone rocks. Both varieties are used for
glass-making. Chalk is a soft friable material which is apt to clog
during the grinding operations, particularly as the natural product
is generally somewhat moist. As regards the greater part of its mass,
chalk is often found in a state of great purity, but it is frequently
contaminated by the presence of scattered masses of flint. Chemically
this impurity is not very objectionable to the glass-maker, since it
merely introduces a small proportion of silica whose presence need
scarcely be allowed for in laying down the mixture. On the other
hand, if any fragments of flint remain in the mixture when put into
the furnace, they prove very refractory, and are apt to be found as
opaque enclosures in the finished glass. Natural limestone can also be
obtained in great purity in many parts of the world. It is generally
a hard and rather brittle rock that can be readily ground to powder
of the requisite degree of fineness. Flint concretions are not so
frequently found in this material, but, on the other hand, it is often
contaminated with magnesia and iron. The former ingredient, when
present in small quantities, tends to make the glass hard and viscous,
so that limestone of the lowest possible magnesia content should be
used, especially for the harder kinds of glass, such as plate and
sheet-glass, etc. The iron contents of the limestone used must also
be low where a white glass is required; but since a smaller quantity
of limestone is used for a given weight of glass produced than the
quantity of sand used for the same purpose, the presence of a somewhat
higher percentage of iron is permissible in the limestone as compared
with the sand; for the better varieties of glass, however, the iron
should not exceed 0·3 per cent. of the limestone.
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