Nowhere is this more urgently needed
than in the whole field of glass manufacture.
The author is indebted to Mr. W. C. Hancock for valuable assistance in
the reading of proofs and various suggestions in connection with the
contents of this book.
TABLE OF CONTENTS
PAGE
PREFACE v
CHAPTER I.
THE PHYSICAL AND CHEMICAL PROPERTIES OF GLASS.
Definition of the term “Glass”--Amorphous structure the
common feature of all vitreous bodies--Glass a congealed
fluid--Glasses not definite chemical compounds but
complex solutions--Range of chemical composition
available for glass-making--Considerations governing
chemical composition--Influence of composition on
physical properties--Chemical stability of glass--
Permanence of glass surfaces--Action of water, acids,
and alkalies on glass--Action of light on glass _p._ 1
CHAPTER II.
THE PHYSICAL PROPERTIES OF GLASS.
Mechanical properties: tensile strength, crushing strength,
elasticity, ductility, and hardness--Thermal properties
of glass: thermal endurance, coefficient of expansion,
thermal conductivity--Thermometer glass--Electrical
properties of glass--Transparency and colour of glass _p._ 18
CHAPTER III.
THE RAW MATERIALS OF GLASS MANUFACTURE.
General considerations--Chemical purity, moisture, and
physical condition, constancy of quality--Sources
of silica, sand and sandstone--Felspar--Sources of
alkali: Soda ash (carbonate of soda), salt-cake (sulphate
of soda), pearl ash (carbonate of potash)--Alkali
nitrates--Natural minerals containing alkalies--Sources
of other bases: Lime, chalk, limestone, slaked lime--
Gypsum (sulphate of lime)--Barium compounds--Magnesia
and zinc--Lead oxide, red lead--Aluminium, manganese,
arsenic--Carbon--Coke, charcoal, anthracite coal _p._ 35
CHAPTER IV.
CRUCIBLES AND FURNACES FOR THE FUSION OF GLASS.
Fire-clay and silica-brick--Manufacture of glass-melting
pots--Drying and first heating of pots--Blocks for tank
and other furnaces--Uses of silica brick--Furnaces--
Coal-fired and gas-fired furnaces--Gas producers--
Regenerative furnaces, principles and construction of
Siemens’ furnaces--Recuperative furnaces--General
arrangements of modern tank furnaces--Relative
advantages of tank and pot furnaces _p._ 54
CHAPTER V.
THE PROCESS OF FUSION.
Mixing of raw materials by hand and by machinery--The
charging operation--Chemical reactions during melting of
carbonate mixtures, and of sulphate mixtures--Influence
of carbon on the reactions--The fining process _p._ 73
CHAPTER VI.
PROCESSES USED IN THE WORKING OF GLASS.
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