Harper's Electricity Book for BoysAdams, Joseph H. (Joseph Henry)
Science
Harper's Electricity Book for Boys
Adams, Joseph H. (Joseph Henry)
Electricity -- Juvenile literature
To make the surface conductive, finely powdered black-lead, or plumbago
of the best kind, or finely pulverized gas-carbon is brushed over the
surface. This must be thoroughly done; and if the deposit is slow about
appearing at any spot it may be hastened by touching it with the end of
an insulated wire attached to the main conductor. This, of course, will
only answer for objects strong enough to stand the brushing treatment;
it will not do for flowers, insects, and other delicate things, that are
to be silver or gold plated. These should be given a film of silver by
soaking in a solution of alcohol and nitrate of silver, made by shaking
two parts of the chemical into one hundred parts of grain-alcohol, with
the aid of heat and in a well-corked bottle. When dry, the object should
be subjected to a bath of sulphuretted hydrogen gas under a hood. The
sulphuretted hydrogen is made by bringing a bar of wrought-iron to a
white-heat in the kitchen range or furnace fire, and touching it with a
stick of sulphur. The iron will melt and drop like wax. These drops
should be collected in a bottle. Now pour over them diluted sulphuric
acid, one part acid to three parts water, and the gas will at once rise.
It will be quickly recognized by its odor, which is similar to that of
over-ripe eggs. It can be led off through a tube to the place where you
wish to use it, and when through, the operation of gas-generation may be
stopped by pouring off the liquid.
All objects prepared in this way should be given a preliminary coating
of thin copper before they are plated with any other metal.
Silver-plating
Plating in silver is done in practically the same way as described for
the coppering process. Thin strips or sheets of pure silver are used for
the anodes, and the electrolyte is composed of nitrate of silver,
cyanide of potassium, and water.
Dissolve three and one-half ounces of nitrate of silver in one gallon of
water; or if more water is needed to fill the tank, add it in the
proportion of three and one-half ounces of the nitrate to each gallon of
water. Dissolve two ounces of cyanide of potassium in a quart of water,
and slowly add this to the nitrate solution. A precipitate of cyanide of
silver will be formed. Keep adding and stirring until no more
precipitate is formed, but be careful not to get an excess of the
cyanide in the solution.
Gather this precipitate, and wash it on filtering-paper by pouring water
over it. The filter-paper should be rolled in a funnel shape thus
permitting the water to run away and leaving the precipitate in the
paper. This precipitate is to be dissolved in more cyanide solution, and
added to the quantity in the tank. There should be about two ounces of
the potassium cyanide per gallon over and above what was originally put
in.
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