Hawkins Electrical Guide v. 01 (of 10): Questions, Answers, & Illustrations, A progressive course of study for engineers, electricians, students and those desiring to acquire a working knowledge of electricity and its applications — John Shaqi
Hawkins Electrical Guide v. 01 (of 10): Questions, Answers, & Illustrations, A progressive course of study for engineers, electricians, students and those desiring to acquire a working knowledge of electricity and its applicationsHawkins, N. (Nehemiah)
Science
Hawkins Electrical Guide v. 01 (of 10): Questions, Answers, & Illustrations, A progressive course of study for engineers, electricians, students and those desiring to acquire a working knowledge of electricity and its applications
Hawkins, N. (Nehemiah)
Electrical engineering -- Handbooks, manuals, etc.
=Action of a Primary Cell.=--The fundamental fact on which the
electro-chemical generation of current depends is, that if a plate of
metal be placed in a liquid there is a difference of electrical condition
produced between them of such sort that the metal either takes a lower or
higher electrical potential than the liquid, according to the nature of
the metal and the liquid. If two different metals be placed in one
electrolytic liquid, then there is a difference of state produced between
them, so that, if joined by wire outside the liquid, a current of
electricity will traverse the wire. This current proceeds in the liquid
from the metal which is most acted upon chemically to that which is least
acted upon.
Referring to fig. 41, the construction and action of a simple primary cell
may be briefly described as follows:
Place in a glass jar some water having a little sulphuric or other acid
added to it. Place in it separately two clean strips, one of zinc, Z, and
one of copper, C. This cell is capable of supplying a continuous flow of
electricity through a wire whose ends are brought into connection with
the two strips. When the current flows, the zinc strip is observed to
waste away, its consumption in fact furnishing the energy or electromotive
force required to drive the current through the cell and the connecting
wire. The cell may therefore be regarded as a kind of chemical furnace in
which the fuel is the zinc.
[Illustration: FIG. 40.--Simple primary cell. It consists of two
dissimilar metal plates (such as copper and zinc which are called the
_elements_), immersed in the _electrolyte_ or exciting fluid contained in
the glass jar.]
=Ques. How are the positive and negative elements of a primary cell
distinguished?=
Ans. The plate attacked by the electrolyte is the negative element, and
the one unattacked the positive element.
=Chemical Changes; Polarization.=--The chemical changes which take place
in a simple cell, consisting of zinc and copper elements in an electrolyte
of dilute sulphuric acid, may be briefly described as follows: When the
two elements are connected and the current commences to flow, the
sulphuric acid acts on the surface of the zinc plate and forms sulphate of
zinc. The formation of this new substance necessitates the liberation of
some of the hydrogen contained in the sulphuric acid, and it will be found
that bubbles of free hydrogen gas speedily appear on the surface of the
negative element, that is, on the copper plate.
While the zinc is being dissolved to form zinc sulphate, hydrogen gas is
liberated from the sulphuric acid.
[Illustration: FIG. 41.--Simple primary cell with circuit closed, showing
direction of the current.]
Some bubbles of the gas rise to the surface of the electrolyte and so
escape into the air, _but much of it clings to the surface of the copper
element which thus gradually becomes covered with a thin film of
hydrogen_.
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