Hawkins Electrical Guide v. 01 (of 10): Questions, Answers, & Illustrations, A progressive course of study for engineers, electricians, students and those desiring to acquire a working knowledge of electricity and its applicationsHawkins, N. (Nehemiah)
Science
Hawkins Electrical Guide v. 01 (of 10): Questions, Answers, & Illustrations, A progressive course of study for engineers, electricians, students and those desiring to acquire a working knowledge of electricity and its applications
Hawkins, N. (Nehemiah)
Electrical engineering -- Handbooks, manuals, etc.
Partly on account of the decreased area of copper plate in contact with
the electrolyte, and partly because the hydrogen tends to produce a
current in the opposite direction, the useful electrical output becomes
considerably diminished and the cell is said to be _polarized_. This state
of affairs may be rectified by stirring up the electrolyte, or by shaking
the cell, so as to assist the hydrogen bubbles to detach themselves from
the surface of the copper plate and make their way to the atmosphere
through the electrolyte. This, however, is only a temporary remedy, as the
polarized condition will soon be reached again, and a further agitation of
the cell will be necessary. Hence, a simple cell of this kind is not
desirable for practical work, and it must be modified to adapt it to
constant use.
When the sulphuric acid in a cell acts in the zinc element and produces
sulphate of zinc, a certain amount of work is done which is manifested
partly in the form of useful electric energy, and partly as heat which
warms the electrolyte and which is thereby lost for all practical
purposes.
=Ques. If the zinc and copper electrodes of a simple cell be not connected
externally what changes take place within the cell?=
Ans. The zinc plate immediately becomes strongly charged with negative
electricity, and the copper plate weakly so. As long as the plates remain
unconnected, and the zinc is pure, no further action takes place.
=Ques. If the electrodes be connected externally what happens?=
Ans. If the plates be connected by a wire outside the electrolyte, the
tendency which dissimilar electrical charges have to neutralize one
another causes a flow of negative electricity through the wire from zinc
to copper, and a positive flow in the opposite direction. The “static”
charge being thus disposed of, a fresh charge is given to the plates by
the action of the acid, which commences to dissolve the zinc. As long as
the wire connects the copper and zinc plates, the acid will continue its
action on the zinc until either acid or zinc is exhausted.
The reader may ask: how can there be a positive flow when both
plates are negatively electrified?
An analogy is the best way to make this point clear: Imagine two
equal vessels, from each of which the air has been partially
exhausted, but from one (A) 10 times as much air has been taken
as from the other (B). Connect A and B by a tube. Now, although
both vessels have less than the atmospheric pressure, that is,
both have “negative” pressures, yet a current of air will flow
from B to A until the pressures in each are equalized; that is,
until both have equal “negative charges” of air.
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