Hawkins Electrical Guide v. 01 (of 10): Questions, Answers, & Illustrations, A progressive course of study for engineers, electricians, students and those desiring to acquire a working knowledge of electricity and its applicationsHawkins, N. (Nehemiah)
Science
Hawkins Electrical Guide v. 01 (of 10): Questions, Answers, & Illustrations, A progressive course of study for engineers, electricians, students and those desiring to acquire a working knowledge of electricity and its applications
Hawkins, N. (Nehemiah)
Electrical engineering -- Handbooks, manuals, etc.
1. Its electromotive force should be high and constant;
2. Its internal resistance should be small;
3. It should be perfectly quiescent when the circuit is open;
4. It should give a constant current, and therefore must be free from
polarization, and not liable to rapid exhaustion;
5. It should be easily cared for, and if possible, should not emit
corrosive fumes;
6. It should be cheap and of durable materials.
=Single and Two Fluid Cells.=--The distinction between a single and a two
fluid cell has already been given. The single fluid cell of Volta with its
zinc and copper plates represents the simplest form of primary cell.
In the _two fluid cell_, the positive (zinc) plate is immersed in the
exciting liquid (usually dilute sulphuric acid) and is decomposed by the
action upon it, while the negative plate is placed in the liquid
depolarizer which is decomposed by the hydrogen arrested by it, thus
preventing polarization.
In some forms of cell, the two liquids are separated by a porous partition
of unglazed earthenware, which, while it prevents the liquids mixing
except very slowly, does not prevent the passage of hydrogen and
electricity.
[Illustration: FIGS. 44 and 45.--Leclanche cell and porous cup. This very
common form of cell is an example of the single fluid type, with a solid
depolarizer surrounding the negative element; the latter is generally
carbon, the positive element being zinc. The liquid used is a strong
solution of ammonium chloride, commonly known as sal-ammoniac, and which
resembles table salt. In the porous cup type of cell, a carbon slab is
placed in the porous cup, and is surrounded by a mixture of small pieces
of carbon and manganese dioxide, the top being covered by means of pitch,
leaving one or two small holes for air and gas to pass through. The
depolarizer will take care of a limited amount of the hydrogen produced
when the cell is on closed circuit, but if the circuit be closed for any
length of time polarization occurs. The cell is thus of the open circuit
class, and will furnish a good current where it is required only
intermittently. Zinc is dissolved only when the cell is being used. This
type of cell, or its modification, is used for gas lighting and bell work.
The cell requires very little attention. Water must be added as the
solution evaporates, and the zinc rod replenished when necessary. The
electromotive force is about 1.48 volts and the internal resistance about
4 ohms.]
Complete depolarization is usually obtained also in single fluid cells,
having in addition a depolarizing solid body, such as oxide of manganese,
oxide of copper, or peroxide of lead, in contact with the carbon pole.
Such cells really do not belong to the single fluid cells, and are
considered in the two fluid class.
A few examples of single and double fluid primary cells will now be
described.
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