Hawkins Electrical Guide v. 01 (of 10): Questions, Answers, & Illustrations, A progressive course of study for engineers, electricians, students and those desiring to acquire a working knowledge of electricity and its applications — John Shaqi
Hawkins Electrical Guide v. 01 (of 10): Questions, Answers, & Illustrations, A progressive course of study for engineers, electricians, students and those desiring to acquire a working knowledge of electricity and its applicationsHawkins, N. (Nehemiah)
Science
Hawkins Electrical Guide v. 01 (of 10): Questions, Answers, & Illustrations, A progressive course of study for engineers, electricians, students and those desiring to acquire a working knowledge of electricity and its applications
Hawkins, N. (Nehemiah)
Electrical engineering -- Handbooks, manuals, etc.
=The Leclanche Cell.=--This cell was invented by Leclanche, a French
electrician, and was the first cell in which sal-ammoniac was used. This
form of cell, as shown in fig. 45, is in general use for electric bells,
its great recommendation being that, once charged, it retains its power
without attention for considerable time.
Two jars are employed in its construction; the outer one is of glass,
contains a zinc rod, and is charged with a solution of ammonium chloride,
called sal-ammoniac.
The inner jar is of porous earthenware, containing a carbon plate, and is
filled with a mixture of manganese peroxide and broken gas carbon. When
the carbon plate and the zinc rod are connected, a steady current of
electricity is set up, the chemical action which takes place being as
follows: _the zinc becomes oxidized by the oxygen from the manganese
peroxide, and is subsequently converted into zinc chloride by the action
of the sal-ammoniac_.
After the battery has been in continuous use for some hours, the manganese
becomes exhausted of oxygen, and the force of the electrical current is
greatly diminished; but if the battery be allowed to rest for a short
time, the manganese obtains a fresh supply of oxygen from the atmosphere,
and is again fit for use.
After about 18 months work, the glass cell will probably require
recharging with sal-ammoniac, and the zinc rod may also need renewing; but
should the porous cell get out of order, it is better to get a new one
than to attempt to recharge it.
The directions for setting up a Leclanche cell are as follows:
1. Place in the glass jar six ounces of sal-ammoniac, and pour
in water until the jar is one-third full, then stir thoroughly.
2. Place the porous cup in the solution, and if necessary add
water until it rises to within 1-1/2 inches of the top of the
porous cup.
3. Put the zinc rod in place and set the cell away (not
connected up), for about 12 hours, so as to allow the liquid to
thoroughly soak into the porous cup. This will lower the level
of the liquid to about one-third the height of the jar. The cell
will then be ready for use. As the level of the liquid is
lowered by evaporation, it should be maintained at the stated
height by adding water.
The Leclanche cell is adapted to open circuit work, being extensively used
for ringing electric bells.
The objections to the Leclanche cell are:
1. Rapid polarization;
2. High internal resistance due to porous pot;
3. Restricted space for electrolyte causing rapid lowering of level of
liquid by evaporation;
4. Eating away of the zinc rod at the surface of the liquid, rendering
the rod useless before the lower part is consumed.
=Fuller Bichromate Cell.=--In the bichromate cells or the chromic acid
cells, bichromate of soda, or bichromate of potassium, is used for the
depolarizer, water and sulphuric acid being added for attacking the zinc.
Public-domain text, read in full here on John Shaqi.
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