Hawkins Electrical Guide v. 01 (of 10): Questions, Answers, & Illustrations, A progressive course of study for engineers, electricians, students and those desiring to acquire a working knowledge of electricity and its applications — John Shaqi
Hawkins Electrical Guide v. 01 (of 10): Questions, Answers, & Illustrations, A progressive course of study for engineers, electricians, students and those desiring to acquire a working knowledge of electricity and its applicationsHawkins, N. (Nehemiah)
Science
Hawkins Electrical Guide v. 01 (of 10): Questions, Answers, & Illustrations, A progressive course of study for engineers, electricians, students and those desiring to acquire a working knowledge of electricity and its applications
Hawkins, N. (Nehemiah)
Electrical engineering -- Handbooks, manuals, etc.
Daniell cells are used especially for electroplating, electrotyping and
telegraphic work. The electromotive force of a single cell is 1.079 volts.
=Directions for Making a Daniell Cell.=--The simple Daniell cell shown in
fig. 52 may be easily made as follows: The outer vessel A, consists of a
glass jar (an ordinary glass jam jar will do) containing a solution of
sulphuric acid (1 part in 12 to 20 parts of water), and a zinc rod B.
Inside the jar is placed a porous pot C containing a strip of thin sheet
copper D, and a saturated solution of sulphate of copper (also called
“blue stone” and “blue vitrol”).
The zinc is preferably of the Leclanche form, which will be found to be
cleaner, more durable, and cheaper than a zinc sheet. The porous pot
should be dipped in melted paraffin wax, both top and bottom, to prevent
the solution mingling too freely and “creeping.” A few crystals of copper
sulphate are placed in the pot as shown.
[Illustration: FIG. 52.--Simple Daniell cell for closed circuit work. To
maintain a constant current for an indefinite time, it is only necessary
to maintain the supply of copper crystals and zinc. The cell as shown in
the figure is easily made by following the direction given in the
accompanying text.]
In mixing the sulphuric acid and water, _the acid should be added to the
water--never the reverse._ Zinc sulphate is sometimes used instead, as it
reduces the wasteful consumption of the zinc, but it should be pure.
With care the cell will last for weeks. When it weakens or “runs down,” an
addition of sulphuric acid to the outer jar and a few more crystals
placed in the porous pot will put the cell in good condition.
[Illustration: FIG. 53.--Daniell gravity cell, “crowfoot” pattern. This is
a two fluid cell in which gravity instead of a porous cup is depended upon
to keep the liquids separate. The two solutions consist of copper sulphate
and dilute sulphuric acid, the elements being made of zinc and copper.]
=Gravity Cells.=--In a two liquid cell, instead of employing a porous cell
to keep the two liquids separate, it is possible, where one of the liquids
is heavier than the other, to arrange that the heavier liquid shall form a
stratum at the bottom of the cell, the lighter floating upon it. Such
arrangements are called _gravity cells_; but the separation is never
perfect, the heavy liquid slowly diffusing upwards.
=Daniell Gravity Cell.=--In this cell, shown in fig. 53, the same elements
are used as in the ordinary Daniell cell, but the porous pot is dispensed
with, the two solutions being separated by the action of gravity as
explained in the preceding paragraph.
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