Hawkins Electrical Guide v. 01 (of 10): Questions, Answers, & Illustrations, A progressive course of study for engineers, electricians, students and those desiring to acquire a working knowledge of electricity and its applicationsHawkins, N. (Nehemiah)
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Hawkins Electrical Guide v. 01 (of 10): Questions, Answers, & Illustrations, A progressive course of study for engineers, electricians, students and those desiring to acquire a working knowledge of electricity and its applications
Hawkins, N. (Nehemiah)
Electrical engineering -- Handbooks, manuals, etc.
[Illustration: FIG. 54.--Partz acid gravity cell. In this form of cell,
the electrolyte which surrounds the zinc is either magnesium sulphate or
common salt. The depolarizer is a bichromate solution which surrounds the
perforated carbon plate located in the bottom of the jar. A vertical
carbon rod fits snugly into the tapered hole in the carbon plate, and
extends through the cover forming the positive pole. The depolarizer,
being heavier than the electrolyte, remains at the bottom of the jar, and
the two liquids are thus kept separate. This depolarizer is placed on the
market in the form of crystals, known as sulpho-chromic salt, made by the
action of sulphuric acid upon chromic acid. When dissolved, its action is
similar to that of the chromic acid solution. After the cell has been set
up with everything else in place, the crystals are introduced into the
solution, near the bottom of the jar, through the vertical glass tube
shown, and slowly dissolve and diffuse over the surface of the carbon
plate. When the cell current weakens a few tablespoonfuls of the salt
introduced through the tube will restore the current to its normal value.
The cell should remain undisturbed to prevent the solution from mixing.
Its electromotive force is from 1.9 to 2 volts, and the 6 in. × 8 in. size
has an internal resistance of about .5 ohm. Since the depolarizer is quite
effective, the cell may be used on open or closed circuit work.]
The copper sulphate solution, being the heavier of the two, rests at the
bottom of the battery jar, while the dilute sulphuric acid remains at the
top. To suit this arrangement the copper and zinc elements are located as
shown, the copper elements being at the bottom, and the zinc element,
shaped like a crow’s foot (hence the name “crowfoot cell”) is suspended at
the top.
The absence of the porous pot decreases the internal resistance, but the
electromotive force is the same as in the ordinary type of Daniell cell.
Public-domain text, read in full here on John Shaqi.
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