Hawkins Electrical Guide v. 01 (of 10): Questions, Answers, & Illustrations, A progressive course of study for engineers, electricians, students and those desiring to acquire a working knowledge of electricity and its applicationsHawkins, N. (Nehemiah)
Science
Hawkins Electrical Guide v. 01 (of 10): Questions, Answers, & Illustrations, A progressive course of study for engineers, electricians, students and those desiring to acquire a working knowledge of electricity and its applications
Hawkins, N. (Nehemiah)
Electrical engineering -- Handbooks, manuals, etc.
[Illustration: FIG. 55.--Wheelock cell; the elements are carbon and zinc.
To set up, place the grid in the bottom of the jar and fill its two
troughs each about half full of mercury. Place the porous cell in position
on the grid so that it sits perfectly upright, resting in the recess of
the latter. The zincs stand with lower ends resting in mercury in the
troughs of the grid. Into the porous cell, to a height of _only
two-thirds_ full, pour solution consisting of equal parts water and
sulphuric acid, by measure. Add to this 1/2 pound nitrate soda, 1 ounce
chromic acid. This solution may be made up in the above proportion and
kept in covered receptacle in any desired quantity, ready for use. In the
outer jar for 6 × 8 size, 2-1/2 pints of water, and 1/2 gill sulphuric
acid, 1 part sulphuric acid to 20 parts water, or as much sulphuric acid
as it will take without boiling. When a charge becomes exhausted it may be
renewed by adding sulphuric acid and salts in the proportions given above,
after drawing out with syringe enough of the old solutions to make room
for the additions, but the best action is obtained with entirely new
solutions. Zincs must be kept thoroughly amalgamated by keeping a good
supply of mercury in the troughs.]
When a current is produced by a Daniell cell:
1. Copper is deposited on the copper plate;
2. Copper sulphate is consumed;
3. The sulphuric acid remains unchanged in quantity;
4. Zinc sulphate is formed;
5. Zinc is consumed.
If, however, the copper sulphate solution be too weak, the water
is decomposed instead of the copper sulphate, and hydrogen is
deposited on the copper plate. This deposit of hydrogen lowers
the voltage, hence care should be taken to maintain an adequate
supply of copper sulphate.
The voltage of a Daniell cell varies from about 1.07 volt to 1.14 volt,
according to the density of the copper sulphate solution and the amount of
zinc sulphate present in the dilute sulphuric acid.
=“Dry” Cells.=--It is often necessary to use cells in places where there
is considerable jarring or motion, as for automobile or marine ignition.
The ordinary cell is not well adapted to this service on account of the
liability of spilling the electrolyte, hence, the introduction of the
so-called dry cell.
A dry cell is composed of two elements, usually zinc and carbon, and a
liquid electrolyte. A zinc cup closed at the bottom and open at the top
forms the negative electrode; this is lined with several layers of
blotting paper or other absorbing material.
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