Heroes of Science: ChemistsMuir, M. M. Pattison (Matthew Moncrieff Pattison)
History
Heroes of Science: Chemists
Muir, M. M. Pattison (Matthew Moncrieff Pattison)
Chemistry -- History; Chemists
But it was very hard to get chemists to adopt these views. As Bacon says,
"If false facts in Nature be once on foot, what through neglect of
examination, the countenance of antiquity, and the use made of them in
discourse, they are scarce ever retracted."
Chemists had long been accustomed to systems which pretended to explain all
chemical facts. The phlogistic theory, which had tyrannized over chemistry,
had been succeeded by the Lavoisierian chemistry, which recognized one
acidifier, and this also the one supporter of combustion. To ascribe these
properties to any element other than oxygen appeared almost profane.
But when Davy spoke of chlorine as an acidifier, he did not use this word
in the same sense as that in which it was employed by the upholders of the
oxygen theory of acids; he simply meant to express the fact that a compound
containing chlorine as one of its constituents, but not containing oxygen,
was a true acid. When Gay-Lussac attempted to prove that hydrogen is an
_alkalizing principle_, Davy said, "This is an attempt to introduce into
chemistry a doctrine of occult qualities, and to refer to some mysterious
and inexplicable energy what must depend upon a peculiar corpuscular
arrangement." And with regard to Gay-Lussac's strained use of analogies
between hydrogen compounds and alkalis, he says, "The substitution of
analogy for fact is the bane of chemical philosophy; the legitimate use of
analogy is to connect facts together, and to guide to new experiments."
But Davy's facts were so well established, and his experiments so
convincing, that before two or three years had passed, most chemists were
persuaded that chlorine was an element--_i.e._ a substance which had never
been decomposed--and that muriatic acid was a compound of this element with
hydrogen.
Berzelius was among the last to adopt the new view. Woehler tells us that in
the winter of 1823, when he was working in the laboratory of Berzelius,
Anna, while washing some basins, remarked that they smelt strongly of
oxidized muriatic acid: "Now," said Berzelius, "listen to me, Anna. Thou
must no longer say 'oxidized muriatic acid,' but 'chlorine;' that is
better."
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account