Heroes of Science: ChemistsMuir, M. M. Pattison (Matthew Moncrieff Pattison)
History
Heroes of Science: Chemists
Muir, M. M. Pattison (Matthew Moncrieff Pattison)
Chemistry -- History; Chemists
This work on chlorine was followed up, in 1813, by the proof that the class
of acidifiers and supporters of combustion contains a third elementary
substance, viz. iodine. As Davy's views regarding acids and salts became
developed, he seems to have more and more opposed the assumption that any
one element is especially to be regarded as the acidifying element; but at
the same time he seems to admit that most, if not all, acids contain
hydrogen. Such oxides as sulphur trioxide, nitrogen pentoxide, etc., do not
possess acid properties except in combination with water. But he of course
did not say that all hydrogen compounds are acids; he rather regarded the
possession by a substance of acid properties as dependent, to a great
extent, on the nature of the elements other than hydrogen which it
contained, or perhaps on the arrangement of all the elements in the
particles of the acid. He regarded the hydrogen in an acid as capable of
replacement by a metal, and to the metallic derivative--as it might be
called--of the acid, thus produced, he gave the name of "salt." An acid
might therefore be a compound of hydrogen with one other element--such were
hydrochloric, hydriodic, hydrofluoric acids--or it might be a compound of
hydrogen with two or more elements, of which one might or might not be
oxygen--such were hydrocyanic acid and chloric or nitric acid. If the
hydrogen in any of these acids were replaced by a metal a salt would be
produced. A salt might therefore contain no oxygen, _e.g._ chloride or
iodide of potassium; but in most cases salts did contain oxygen, _e.g._
chlorate or nitrate of potassium.
Acids were thus divided into oxyacids (or acids which contain oxygen) and
acids containing no oxygen; the former class including most of the known
acids. The old view of salts as being compounds of acids (_i.e._ oxides of
the non-metallic elements) and bases (_i.e._ oxides of metals) was
overthrown, and salts came to be regarded as metallic derivatives of acids.
From this time, these terms--acids, salts, bases--become of less importance
than they formerly were in the history of chemical advance.
In trying to explain Davy's electro-chemical theory I have applied the word
_affinity_ to the mutual action and reaction between two substances which
combine together to form a chemical compound. It is now necessary that we
should look a little more closely into the history of this word _affinity_.
Oil and water do not mix together, but oil and potash solution do; the
former may be said not to have, and the latter to have, an affinity one for
the other. When sulphur is heated, the yellow odourless solid, seizing upon
oxygen in the air, combines with it to produce a colourless strongly
smelling gas. Sulphur and oxygen are said to have strong affinity for each
other.
Public-domain text, read in full here on John Shaqi.
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