Heroes of Science: ChemistsMuir, M. M. Pattison (Matthew Moncrieff Pattison)
History
Heroes of Science: Chemists
Muir, M. M. Pattison (Matthew Moncrieff Pattison)
Chemistry -- History; Chemists
If equal weights of lime and magnesia be thrown into diluted nitric acid,
after a time it is found that some of the lime, but very little of the
magnesia, is dissolved. If an aqueous solution of lime be added to a
solution of magnesia in nitric acid, the magnesia is precipitated in the
form of an insoluble powder, while the lime remains dissolved in the acid.
It is said that lime has a stronger affinity for nitric acid than magnesia
has. Such reactions as these used to be cited as examples of _single
elective affinity_--single, because one substance combined with one other,
and elective, because a substance seemed to choose between two others
presented to it, and to combine with one to the exclusion of the other.
But if a neutral solution of magnesia in sulphuric acid is added to a
neutral solution of lime in nitric acid, sulphate of lime and nitrate of
magnesia are produced. The lime, it was said, leaves the nitric and goes
to the sulphuric acid, which, having been deserted by the magnesia, is
ready to receive it; at the same time the nitric acid from which the lime
has departed combines with the magnesia formerly held by the sulphuric
acid. Such a reaction was said to be an instance of _double affinities_.
The chemical changes were caused, it was said, by the simultaneous affinity
of lime for sulphuric acid, which was greater than its affinity for nitric
acid, and the affinity of magnesia for nitric acid, which was greater than
its affinity for sulphuric acid.
If a number of salts were mixed, each base--supposing the foregoing
statements to be correct--would form a compound with that acid for which it
had the greatest affinity. It should then be possible to draw up tables of
affinity. Such tables were indeed prepared. Here is an example:--
_Sulphuric Acid._
Baryta. Lime.
Strontia. Ammonia.
Potash. Magnesia.
Soda.
This table tells us that the affinity of baryta for sulphuric acid is
greater than that of strontia for the same acid, that of strontia greater
than that of potash, and so on. It also tells that potash will decompose a
compound of sulphuric acid and soda, just as soda will decompose a compound
of the same acid with lime, or strontia will decompose a compound with
potash, etc.
Public-domain text, read in full here on John Shaqi.
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