Heroes of Science: ChemistsMuir, M. M. Pattison (Matthew Moncrieff Pattison)
History
Heroes of Science: Chemists
Muir, M. M. Pattison (Matthew Moncrieff Pattison)
Chemistry -- History; Chemists
But Berthollet showed in the early years of this century that a large
quantity of a body having a weak affinity for another will suffice to
decompose a small quantity of a compound of this other with a third body
for which it has a strong affinity. He showed, that is, that the formation
or non-formation of a compound is dependent not only on the so-called
affinities between the constituents, but also on the relative quantities of
these constituents. Berthollet and other chemists also showed that affinity
is much conditioned by temperature; that is, that two substances which show
no tendency towards chemical union at a low temperature may combine when
the temperature is raised. He, and they, also proved that the formation or
non-formation of a compound is much influenced by its physical properties.
Thus, if two substances are mixed in solution, and if by their mutual
action a substance can be produced which is insoluble in the liquids
present, that substance is generally produced whether the affinity between
the original pair of substances be strong or weak.
The outcome of Berthollet's work was that tables of affinity became almost
valueless. To say that the affinity of this body for that was greater than
its affinity for a third body was going beyond the facts, because the
formation of this or that compound depended on many conditions much more
complex than those connoted by the term "affinity." Yet the conception of
affinity remained, although it could not be applied in so rigorous a way as
had been done by the earlier chemists. If an element, A, readily combines
with another element, B, under certain physical conditions, but does not,
under the same conditions, combine with a third element, C, it may still be
said that A and B have, and A and C have not, an affinity for each other.
Public-domain text, read in full here on John Shaqi.
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