Heroes of Science: ChemistsMuir, M. M. Pattison (Matthew Moncrieff Pattison)
History
Heroes of Science: Chemists
Muir, M. M. Pattison (Matthew Moncrieff Pattison)
Chemistry -- History; Chemists
This general conception of affinity was applied by Berzelius to the atoms
of elements. Affinity, said Berzelius, acts between unlike atoms, and
causes them to unite to form a compound atom, unlike either of the original
atoms; cohesion, on the other hand, acts between like atoms, causing them
to hold together without producing any change in their properties. Affinity
varies in different elements. Thus the affinity of gold for oxygen is very
small; hence it is that gold is found in the earth in the metallic state,
while iron, having a great affinity for oxygen, soon rusts when exposed to
air, or when buried in the earth. Potassium and sodium have great
affinities for oxygen, chlorine, etc.; yet the atoms of potassium and
sodium do not themselves combine. The more any elements are alike
chemically the smaller is their affinity for each other; the more any
elements are chemically unlike the greater is their mutual affinity; but
this affinity is modified by circumstances. Thus, said Berzelius, if equal
numbers of atoms of A and B, having equal or nearly equal affinity for C,
mutually react, compound atoms, AC and BC, will be produced, but atoms of A
and B will remain. The amounts of AC and BC produced will be influenced by
the greater or less affinity of A and B for C; but if there be a greater
number of A than of B atoms, a greater amount of AC than of BC will be
produced. In these cases all the reacting substances and the products of
the actions are supposed to be liquids; but BC, if a solid substance, will
be produced even if the affinity of A for C is greater than that of B for
C.
In some elements, Berzelius taught, affinity slumbers, and can be awakened
only by raising the temperature. Thus carbon in the form of coal has no
affinity for oxygen at ordinary temperatures; it has remained for ages in
the earth without undergoing oxidation; but when coal is heated the
affinities of carbon are awakened, combination with oxygen occurs, and heat
is produced.
Public-domain text, read in full here on John Shaqi.
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