Heroes of Science: ChemistsMuir, M. M. Pattison (Matthew Moncrieff Pattison)
History
Heroes of Science: Chemists
Muir, M. M. Pattison (Matthew Moncrieff Pattison)
Chemistry -- History; Chemists
But why is it that certain elementary atoms exhibit affinity for certain
others? It depends, said Berzelius, on the electrical states of these
atoms. According to the Berzelian theory, every elementary atom has
attached to it a certain quantity of electricity, part of which is positive
and part negative. This electricity is accumulated at two points on each
atom, called respectively the positive pole and the negative pole; but in
each atom one of these electricities so much preponderates over the other
as to give the whole atom the character of either a positively or a
negatively electrified body. When two atoms combine chemically the positive
electricity in one neutralizes the negative electricity in the other. As we
know that similar electricities repel, and opposite electricities attract
each other, it follows that a markedly positive atom will exhibit strong
affinity for a markedly negative atom, less strong affinity for a feebly
negative, and little or no affinity for a positively electrified atom; but
two similarly electrified atoms may exhibit affinity, because in every
positive atom there is some negative electricity, as in every negative atom
there is some positive electricity. Thus, in the atoms of copper and zinc
positive electricity predominates, said Berzelius, but the zinc atoms are
more positive than those of copper; hence, when the metals are brought into
contact the negative electricity of the copper atoms is attracted and
neutralized by the positive electricity of the zinc atoms, combination
takes place, and the compound atom is still characterized by a predominance
of positive electricity.
Hence Berzelius identified "electrical polarity" with chemical affinity.
Every atom was regarded by him as _both_ positively _and_ negatively
electrified; but as one of these electricities was always much stronger
than the other, every atom regarded as a whole appeared to be _either_
positively _or_ negatively electrified. Positive atoms showed affinity for
negative atoms, and _vice versa_. As a positive atom might become more
positive by increasing the temperature of the atom, so might the affinity
of this atom for that be more marked at high than at low temperatures.
Public-domain text, read in full here on John Shaqi.
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