Heroes of Science: ChemistsMuir, M. M. Pattison (Matthew Moncrieff Pattison)
History
Heroes of Science: Chemists
Muir, M. M. Pattison (Matthew Moncrieff Pattison)
Chemistry -- History; Chemists
One of the most commonly occurring and most noticeable changes in the
properties of matter is that which proceeds when a piece of wood, or a
candle, or a quantity of oil burns. The solid wood, or candle, or the
liquid oil slowly disappears, and this disappearance is attended with the
visible formation of flame. Even the heavy fixed metals, tin or lead, may
be caused to burn; light is produced, a part of the metal seems to
disappear, and a white (or reddish) solid, very different from the original
metal, remains. The process of burning presents all those peculiarities
which are fitted to strike an observer of the changes of Nature; that is,
which are fitted to strike a chemist--for chemistry has always been
recognized as having for its object to explain the changes which matter
undergoes. The chemists of the seventeenth and eighteenth centuries were
chiefly occupied in trying to explain this process of burning or
combustion.
Van Helmont (1577-1644), who was a physician and chemist of Brussels,
clearly distinguished between common air and other "airs" or gases produced
in different ways. Robert Hooke (1635-1703), one of the original Fellows of
the Royal Society, in the "Micographia, or Philosophical Description of
Minute Bodies," published in 1665, concluded from the results of numerous
experiments that there exists in common air a peculiar kind of gas, similar
to, or perhaps identical with the gas or air which is got by heating
saltpetre; and he further supposed that when a solid burns, it is dissolved
by (or we should now say, it is converted into a gas by combining with)
this peculiar constituent of the air.
John Mayow (1645-1679), a physician of Oxford, experimented on the basis of
facts established by Hooke. He showed that when a substance, _e.g._ a
candle, burns in air, the volume of air is thereby lessened. To that
portion of the air which had _dissolved_ the burned substance he gave the
name of _nitre-air_, and he argued that this air exists in condensed form
in nitre, because sulphur burns when heated with nitre in absence of common
air. Mayow added the most important fact--a fact which was forgotten by
many later experimenters--that the solid substance obtained by burning a
metal in air weighs more than the metal itself did before burning. He
explained this increase in weight by saying that the burning metal absorbs
particles of "nitre-air" from the atmosphere. Thus Hooke and Mayow had
really established the fact that common air consists of more than one
definite kind of matter--in other words, that common air is not an element;
but until recent times the term "element" or "elementary principle" was
used without any definite meaning. When we say that the ancients and the
alchemists recognized four elements--earth, air, fire, and water--we do not
attach to the word "element" the same definite meaning as when we now say,
"Iron is an element."
Public-domain text, read in full here on John Shaqi.
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