Heroes of Science: ChemistsMuir, M. M. Pattison (Matthew Moncrieff Pattison)
History
Heroes of Science: Chemists
Muir, M. M. Pattison (Matthew Moncrieff Pattison)
Chemistry -- History; Chemists
From earth, air, fire and water other substances were obtained; or it might
be possible to resolve other substances into one or more of these four. But
even to such a word as "substance" or "matter" no very definite meaning
could be attached. Although, therefore, the facts set forth by Hooke and
Mayow might now justify the assertion that air is not an element, they did
not, in the year 1670, necessarily convey this meaning to men's minds. The
distinction between element and compound was much more clearly laid down by
the Hon. Robert Boyle (1627-1691), whose chemical work was wonderfully
accurate and thorough, and whose writings are characterized by acute
scientific reasoning. We shall again return to these terms "element" and
"compound."
But the visible and striking phenomenon in most processes of burning is the
production of light and sometimes of flame. The importance of the fact
that the burned substance (when a solid) weighs more than the unburned
substance was overshadowed by the apparent importance of the outward part
of the process, which could scarcely be passed over by any observer. There
appears to be an outrush of _something_ from the burning substance. There
_is_ an outrush of something, said Becher and Stahl, and this something is
the "principle of fire." The principle of fire, they said, is of a very
subtle nature; its particles, which are always in very rapid motion, can
penetrate any substance, however dense. When metals burn--the argument
continued--they lose this principle of fire; when the burned metal--or
_calx_ as it was usually called--is heated with charcoal it regains this
"principle," and so the metal is re-formed from the calx.
Thus arose the famous theory of _phlogiston_ (from Greek, = "burned"),
which served as a central nucleus round which all chemical facts were
grouped for nearly a hundred years.
John Joachim Becher was born at Speyer in 1635, and died in 1682; in his
chemical works, the most important of which is the "Physica Subterranea,"
he retained the alchemical notion that the metals are composed of three
"principles"--the nitrifiable, the combustible, and the mercurial--and
taught that during calcination the combustible and mercurial principles are
expelled, while the nitrifiable remains in the calx.
George Ernest Stahl--born at Anspach in 1660, and died at Berlin in
1734--had regard chiefly to the principles which escape during the
calcination of metals, and simplifying, and at the same rendering more
definite the idea of Becher, he conceived and enunciated the theory of
phlogiston.
But if _something_ (name it "phlogiston" or call it by any other name you
please) is lost by a metal when the metal is burned, how is it that the
loss of this thing is attended with an increase in the weight of the matter
which loses it? Either the theory of phlogiston must be abandoned, or the
properties of the _thing_ called phlogiston must be very different from
those of any known kind of matter.
Public-domain text, read in full here on John Shaqi.
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