Heroes of Science: ChemistsMuir, M. M. Pattison (Matthew Moncrieff Pattison)
History
Heroes of Science: Chemists
Muir, M. M. Pattison (Matthew Moncrieff Pattison)
Chemistry -- History; Chemists
Stahl replied, phlogiston is a "principle of levity;" the presence of
phlogiston in a substance causes that substance to weigh less than it did
before it received this phlogiston.
In criticizing this strange statement, we must remember that in the middle
of the seventeenth century philosophers in general were not firmly
convinced of the truth that the essential character of matter is that it
possesses weight, nor of the truth that it is impossible to destroy or to
create any quantity of matter however small. It was not until the
experimental work of Lavoisier became generally known that chemists were
convinced of these truths. Nevertheless, the opponents of the Stahlian
doctrine were justified in asking for further explanations--in demanding
that some other facts analogous to this supposed fact, viz. that a
substance can weigh less than nothing, should be experimentally
established.
The phlogistic theory however maintained its ground; we shall find that it
had a distinct element of truth in it, but we shall also find that it did
harm to scientific advance. This theory was a wide and sweeping
generalization from a few facts; it certainly gave a central idea around
which some facts might be grouped, and it was not very difficult, by
slightly cutting down here and slightly adding there, to bring many new
discoveries within the general theory.
We now know that in order to explain the process of combustion much more
accurate knowledge was required than the chemists of the seventeenth
century possessed; but we ought to be thankful to these chemists, and
notably to Stahl, that they did not hesitate to found a generalization on
the knowledge they had. Almost everything propounded in natural science has
been modified as man's knowledge of nature has become wider and more
accurate; but it is because the scientific student of nature uses the
generalizations of to-day as stepping-stones to the better theories of
to-morrow, that science grows "from more to more."
Looking at the state of chemistry about the middle of the eighteenth
century, we find that the experiments, and especially the measurements, of
Hooke and Mayow had laid a firm basis of fact concerning the process of
combustion, but that the phlogistic theory, which appeared to contradict
these facts, was supreme; that the existence of airs, or gases, different
from common air was established, but that the properties of these airs were
very slightly and very inaccurately known; that Boyle had distinguished
element from compound and had given definite meanings to these terms, but
that nevertheless the older and vaguer expression, "elementary principle,"
was generally used; and lastly, that very few measurements of the masses of
the different kinds of matter taking part in chemical changes had yet been
made.
FOOTNOTES:
Public-domain text, read in full here on John Shaqi.
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