Heroes of Science: ChemistsMuir, M. M. Pattison (Matthew Moncrieff Pattison)
History
Heroes of Science: Chemists
Muir, M. M. Pattison (Matthew Moncrieff Pattison)
Chemistry -- History; Chemists
"Thirdly. To mention some of the attempts which have been made to discover
the nature of heat, or to form an idea of what may be the immediate cause
of it.
"Fourthly and lastly. I shall begin to describe sensible effects produced
by heat on the bodies to which it is communicated.
"Any person who reflects on the ideas which we annex to the word _heat_
will perceive that this word is used for two meanings, or to express two
different things. It either means a sensation excited in our organs, or a
certain quality, affection, or condition of the bodies around us, by which
they excite in us that sensation. The word is used in the first sense when
we say, we feel heat; in the second, when we say, there is heat in the fire
or in a hot stone. There cannot be a sensation of heat in the fire, or in
the hot stone, but the matter of the fire, or of the stone, is in a state
or condition by which it excites in us the sensation of heat.
"Now, in beginning to treat of heat and its effects, I propose to use the
word in this second sense only; or as expressing that state, condition, or
quality of matter by which it excites in us the sensation of heat. This
idea of heat will be modified a little and extended as we proceed, but the
meaning of the word will continue at bottom the same, and the reason of the
modification will be easily perceived."
Black's manner of dealing with the phenomenon of combustion illustrates the
clearness of the conceptions which he formed of natural phenomena, and
shows moreover the thoroughly unbiased nature of his mind. As soon as he
had convinced himself that the balance of evidence was in favour of the new
(antiphlogistic) theory, he gave up those doctrines in which he had been
trained, and accepted the teaching of the French chemists; but he did
not--as some with less well-balanced minds might do--regard the new theory
as a final statement, but rather as one stage nearer the complete
explanation which future experiments and future reasoning would serve to
establish.
In his lectures on combustion Black first of all establishes the facts,
that when a body is burned it is changed into a kind (or kinds) of matter
which is no longer inflammable; that the presence of air is needed for
combustion to proceed; that the substance must be heated "to a certain
degree" before combustion or inflammation begins; that this degree of heat
(or we should now say this degree of temperature) differs for each
combustible substance; that the supply of air must be renewed if the
burning is to continue; and that the process of burning produces a change
in the quality of the air supplied to the burning body.
He then states the phlogistic interpretation of these phenomena: that
combustion is caused by the outrush from the burning body of a something
called the _principle of fire_, or _phlogiston_.
Public-domain text, read in full here on John Shaqi.
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