Heroes of Science: ChemistsMuir, M. M. Pattison (Matthew Moncrieff Pattison)
History
Heroes of Science: Chemists
Muir, M. M. Pattison (Matthew Moncrieff Pattison)
Chemistry -- History; Chemists
Black then proceeds to demonstrate certain other facts:--When the
substances produced by burning phosphorus or sulphur are heated with carbon
(charcoal) the original phosphorus or sulphur is reproduced. This
reproduction is due, according to the phlogistic chemists, to the giving
back, by carbon, of the phlogiston which had escaped during the burning.
Hence carbon contains much phlogiston. But as a similar reproduction of
phosphorus or sulphur, from the substances obtained by burning these
bodies, can be accomplished by the use of substances other than carbon, it
is evident that these other substances also contain much phlogiston, and,
moreover, that the phlogiston contained in all these substances is one and
the same _principle_. What then, he asks, is this "principle" which can so
escape, and be so restored by the action of various substances? He then
proceeds as follows:--
"But when we inquire further, and endeavour to learn what notion was formed
of the nature of this principle, and what qualities it was supposed to have
in its separate state, we find this part of the subject very obscure and
unsatisfactory, and the opinions very unsettled.
"The elder chemists, and the alchemists, considered sulphur as the
universal inflammable principle, or at least they chose to call the
inflammable part of all bodies, that are more or less inflammable, by the
name of their sulphur.... The famous German chemist Becher was, I believe,
the first who rejected the notion of sulphur being the principle of
inflammability in bodies.... His notion of the nature of the pure principle
of inflammability was afterwards more fully explained and supported by
Professor Stahl, who, agreeably to the doctrine of Becher, represented the
principle of inflammability as a dry substance, or of an earthy nature, the
particles of which were exquisitely subtile, and were much disposed to be
agitated and set in motion with inconceivable velocity.... The opinion of
Becher and Stahl concerning this _terra secunda_, or _terra inflammabilis_,
or _phlogiston_, was that the atoms of it are, more than all others,
disposed to be affected with an excessively swift whirling motion (_motus
vorticillaris_). The particles of other elementary substances are likewise
liable to be affected with the same sort of motion, but not so liable as
those of _terra secunda_; and when the particles of any body are agitated
with this sort of motion, the body exhibits the phenomena of heat, or
ignition, or inflammation according to the violence and rapidity of the
motion.... Becher and Stahl, therefore, did not suppose that heat depended
on the abundance of a peculiar matter, such as the matter of heat or fire
is now supposed to be, but on a peculiar motion of the particles of
matter....
Public-domain text, read in full here on John Shaqi.
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