Heroes of Science: ChemistsMuir, M. M. Pattison (Matthew Moncrieff Pattison)
History
Heroes of Science: Chemists
Muir, M. M. Pattison (Matthew Moncrieff Pattison)
Chemistry -- History; Chemists
"This very crude opinion of the earthy nature of the principle of
inflammability appears to have been deduced from a quality of many of the
inflammable substances, by which they resist the action of water as a
solvent. The greater number of the earthy substances are little, or not at
all, soluble in water.... And when Becher and Stahl found those compounds,
which they supposed contained phlogiston in the largest quantity, to be
insoluble in water, although the other matter, with which the phlogiston
was supposed to be united, was, in its separate state, exceedingly soluble
in that fluid, they concluded that _a dry nature, or an incapability to be
combined with water_, was an eminent quality of their phlogiston; and this
was what they meant by calling it an earth or earthy substance.... But
these authors supposed, at the same time, that the particles of this dry
and earthy phlogiston were much disposed to be excessively agitated with a
whirling motion; which whirling motion, exerted in all directions from the
bodies in which phlogiston is contained, produced the phenomena of
inflammation. This appears to have been the notion formed by Becher and
Stahl, concerning the nature of the principle of inflammability, or the
phlogiston; a notion which seems the least entitled to the name of
explanation of anything we can think of. I presume that few persons can
form any clear conception of this whirling motion, or, if they can, are
able to explain to themselves how it produces, or can produce, anything
like the phenomena of heat or fire."
Black then gives a clear account of the experiments of Priestley and
Lavoisier (see pp. 58, 59, and 87-89), which established the presence, in
common air, of a peculiar kind of gas which is especially concerned in the
processes of combustion; he emphasizes the fact that a substance increases
in weight when it is burned; and he gives a simple and clear statement of
that explanation of combustion which is now accepted by all, and which does
not require that the existence of any principle of fire should be assumed.
It is important to note that Black clearly connects the _physical_ fact
that heat is absorbed, or evolved, by a substance during combustion, with
the _chemical_ changes which are brought about in the properties of the
substance burned. He concludes with an admirable contrast between the
phlogistic theory and the theory of Lavoisier, which shows how wide, and at
the same time how definite, his conceptions were. Black never speaks
contemptuously of a theory which he opposes.
Public-domain text, read in full here on John Shaqi.
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