Heroes of Science: ChemistsMuir, M. M. Pattison (Matthew Moncrieff Pattison)
History
Heroes of Science: Chemists
Muir, M. M. Pattison (Matthew Moncrieff Pattison)
Chemistry -- History; Chemists
which is reduced from the cut in Priestley's "Air.")
[Illustration: Fig. 1.]
Priestley tells us that at this time he knew very little chemistry, but he
thinks that this was a good thing, else he might not have been led to make
so many new discoveries as he did afterwards make.
Experimenting with fixed air, he found that water could be caused to
dissolve some of the gas. In 1772 he published a pamphlet on the method of
impregnating water with fixed air; this solution of fixed air in water was
employed medicinally, and from this time we date the manufacture of
artificial mineral waters.
The next six years of Priestley's life (1773-1779) are very important in
the history of chemistry; it was during these years that much of his best
work on various airs was performed. During this time he lived as a kind of
literary companion (nominally as librarian) with the Earl of Shelburne
(afterwards Marquis of Lansdowne.) His wife and family--he had now three
children--lived at Calne, in Wiltshire, near Lord Shelburne's seat of
Bowood. Priestley spent most of the summer months with his family, and the
greater part of each winter with Lord Shelburne at his London residence;
during this time he also travelled in Holland and Germany, and visited
Paris in 1774.
In a paper published in November 1772, Priestley says that he examined a
specimen of air which he had extracted from saltpetre above a year before
this date. This air "had by some means or other become noxious, but," he
supposed, "had been restored to its former wholesome state, so as to
effervesce with nitrous air" (in modern language, to combine with nitric
oxide) "and to admit a candle to burn in it, in consequence of agitation
with water." He tells us, in his "Observations on Air" (1779), that at this
time he was altogether in the dark as to the nature of this air obtained
from saltpetre. In August 1774, he was amusing himself by observing the
action of heat on various substances--"without any particular view," he
says, "except that of extracting air from a variety of substances by means
of a burning lens in quicksilver, which was then a new process with me, and
which I was very proud of"--when he obtained from _red precipitate_ (oxide
of mercury) an air in which a candle burned with a "remarkably vigorous
flame." The production of this peculiar air "surprised me more than I can
well express;" "I was utterly at a loss how to account for it." At first he
thought that the specimen of _red precipitate_ from which the air had been
obtained was not a proper preparation, but getting fresh specimens of this
salt, he found that they all yielded the same kind of air. Having satisfied
himself by experiment that this peculiar air had "all the properties of
common air, only in much greater perfection," he gave to it the name of
_dephlogisticated air_. Later experiments taught him that the same air
might be obtained from red lead, from manganese oxide, etc., by the action
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