Heroes of Science: ChemistsMuir, M. M. Pattison (Matthew Moncrieff Pattison)
History
Heroes of Science: Chemists
Muir, M. M. Pattison (Matthew Moncrieff Pattison)
Chemistry -- History; Chemists
of heat, and from various other salts by the action of acids.
Priestley evidently regards the new "dephlogisticated air" simply as very
pure ordinary air; indeed, he seems to look on all airs, or gases, as
easily changeable one into the other. He always interprets his experimental
results by the help of the theory of phlogiston. One would indeed think
from Priestley's papers that the existence of this substance phlogiston was
an unquestioned and unquestionable fact. Thus, he says in the preface to
his "Experiments on Air:" "If any opinion in all the modern doctrine
concerning air be well founded, it is certainly this, that nitrous air is
highly charged with phlogiston, and that from this quality only it renders
pure air noxious.... If I have completely ascertained anything at all
relating to air it is this." Priestley thought that "very pure air" would
take away phlogiston from some metals without the help of heat or any acid,
and thus cause these metals to rust. He therefore placed some clean iron
nails in _dephlogisticated air_ standing over mercury; after three months
he noticed that about one-tenth of the air in the vessel had disappeared,
and he concluded, although no rust appeared, that the dephlogisticated air
had as a fact withdrawn phlogiston from the iron nails. This is the kind of
reasoning which Black described to his pupils as "mere waste of time and
ingenuity." The experiment with the nails was made in 1779; at this time,
therefore, Priestley had no conception as to what his _dephlogisticated
air_ really was.
Trying a great many experiments, and finding that the new air was obtained
by the action of acids on earthy substances, Priestley was inclined to
regard this air, and if this then all other airs, as made up of an acid (or
acids) and an earthy substance. We now know how completely erroneous this
conclusion was, but we must remember that in Priestley's time chemical
substances were generally regarded as of no very definite or fixed
composition; that almost any substance, it was supposed, might be changed
into almost any other; that no clear meaning was attached to the word
"element;" and that few, if any, careful measurements of the quantities of
different kinds of matter taking part in chemical actions had yet been
made.
But at the same time we cannot forget that the books of Hooke and Mayow had
been published years before this time, and that twenty years before
Priestley began his work on airs, Black had published his exact, scientific
investigation on fixed air.
Although we may agree with Priestley that, had he made himself acquainted
with what others had done before he began his own experiments, he might not
have made so many new discoveries as he did, yet one cannot but think that
his discoveries, although fewer, would have been more accurate.
Public-domain text, read in full here on John Shaqi.
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