Heroes of Science: ChemistsMuir, M. M. Pattison (Matthew Moncrieff Pattison)
History
Heroes of Science: Chemists
Muir, M. M. Pattison (Matthew Moncrieff Pattison)
Chemistry -- History; Chemists
"As this discovery appears to me one of the most
interesting which has been made since Stahl, I thought
it expedient to secure to myself the property, by
depositing the present note in the hands of the
Secretary of the Academy, to remain secret till the
period when I shall publish my experiments.
"LAVOISIER.
"Paris, 11th November 1772."
In his paper "On the Calcination of Tin in Closed Vessels, and on the Cause
of Increase of Weight acquired by the Metal during this Process" (published
in 1774), we see and admire Lavoisier's manner of working. A weighed
quantity (about half a pound) of tin was heated to melting in a glass
retort, the beak of which was drawn out to a very small opening; the air
within the retort having expanded, the opening was closed by melting the
glass before the blowpipe. The weight of retort and tin was now noted; the
tin was again heated to its melting point, and kept at this temperature as
long as the process of calcination appeared to proceed; the retort and its
contents were then allowed to cool and again weighed. No change was caused
by the heating process in the total weight of the whole apparatus. The end
of the retort beak was now broken off; air rushed in with a hissing sound.
The retort and contents were again weighed, and the increase over the
weight at the moment of sealing the retort was noted. The calcined tin in
the retort was now collected and weighed. It was found that the increase in
the weight of the tin was equal to the weight of the air which rushed into
the retort. Hence Lavoisier concluded that the calcination of tin was
accompanied by an absorption of air, and that the difference between the
weights of the tin and the calx of tin was equal to the weight of air
absorbed; but he states that probably only a part of the air had combined
with the tin, and that hence air is not a simple substance, but is composed
of two or more constituents.
Between the date of this publication and that of Lavoisier's next paper on
combustion we know that Priestley visited Paris. In his last work, "The
Doctrine of Phlogiston established" (published in 1800), Priestley says,
"Having made the discovery of dephlogisticated air some time before I was
in Paris in 1774, I mentioned it at the table of Mr. Lavoisier, when most
of the philosophical people in the city were present; saying that it was a
kind of air in which a candle burned much better than in common air, but I
had not then given it any name. At this all the company, and Mr. and Mrs.
Lavoisier as much as any, expressed great surprise. I told them that I had
got it from _precipitatum per se_, and also from _red lead_."
Public-domain text, read in full here on John Shaqi.
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