Heroes of Science: ChemistsMuir, M. M. Pattison (Matthew Moncrieff Pattison)
History
Heroes of Science: Chemists
Muir, M. M. Pattison (Matthew Moncrieff Pattison)
Chemistry -- History; Chemists
In 1775 Lavoisier's paper, "On the Nature of the Principle which combines
with the Metals during their Calcination, and which augments their Weight,"
was read before the Academy. The preparation and properties of an air
obtained, in November 1774, from _red precipitate_ are described, but
Priestley's name is not mentioned. It seems probable, however, that
Lavoisier learned the existence and the mode of preparation of this air
from Priestley;[5] but we have seen that even in 1779 Priestley was quite
in the dark as to the true nature of the air discovered by him (p. 60).
In papers published in the next three or four years Lavoisier gradually
defined and more thoroughly explained the phenomenon of combustion. He
burned phosphorus in a confined volume of air, and found that about
one-fourth of the air disappeared, that the residual portion of air was
unable to support combustion or to sustain animal life, that the phosphorus
was converted into a white substance deposited on the sides of the vessel
in which the experiment was performed, and that for each grain of
phosphorus used about two and a half grains of this white solid were
obtained. He further described the properties of the substance produced by
burning phosphorus, gave it the name of _phosphoric acid_, and described
some of the substances formed by combining it with various bases.
The burning of candles in air was about this time studied by Lavoisier. He
regarded his experiments as proving that the air which remained after
burning a candle, and in which animal life could not be sustained, was
really present before the burning; that common air consisted of about
one-fourth part of dephlogisticated air and three-fourths of _azotic air_
(_i.e._ air incapable of sustaining life); and that the burning candle
simply combined with, and so removed the former of these, and at the same
time produced more or less fixed air.
Public-domain text, read in full here on John Shaqi.
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