History of Chemistry, Volume 2 (of 2): From 1850 to 1910Thorpe, T. E. (Thomas Edward)
History
History of Chemistry, Volume 2 (of 2): From 1850 to 1910
Thorpe, T. E. (Thomas Edward)
Chemistry -- History
│Robert Wilhelm Bunsen│ was born at Göttingen on March 31, 1811, and
after studying chemistry under Stromeyer, the discoverer of cadmium,
went to Paris and worked with Gay Lussac. In 1836 he succeeded Wöhler
as teacher of chemistry in the Polytechnic School of Cassel, and in
1842 became Professor of Chemistry in the University of Marburg. In
1852 he was called to Heidelberg, and occupied the Chair of Chemistry
there until his retirement in 1889. He died at Heidelberg on August 16,
1899.
[Illustration: BUNSEN, KIRCHHOFF, AND ROSCOE.]
Bunsen first distinguished himself by his classical work on the
_cacodyl compounds_, obtained as the result of an inquiry into the
nature of the so-called “fuming liquor of Cadet,” an evil-smelling,
highly poisonous, inflammable liquid formed by heating arsenious oxide
with an alkaline acetate. The investigation (1837–1845) is noteworthy,
not only for the skill it exhibits in dealing with a difficult and
highly dangerous manipulative problem, but also for the remarkable
nature of its results and on account of their influence on contemporary
chemical theory. The research, in the words of Berzelius, was the
foundation-stone of the theory of compound radicals. The name _cacodyl_
or _kakodyl_ was suggested by Berzelius in allusion to the nauseous
smell of the compounds of the new radical _arsinedimethyl, As (CH3)2_,
as it was subsequently termed by Kolbe.
Bunsen greatly improved the methods of gasometric analysis; these he
applied, in conjunction with Playfair, to an examination of the gaseous
products of the blast furnace in the manufacture of iron, and thereby
demonstrated the enormous waste of energy occasioned by allowing
the gases to escape unused into the air, as was then the universal
practice. This inquiry effected a revolution in the manufacture of iron
as important, indeed, as that due to the introduction of the hot blast.
Public-domain text, read in full here on John Shaqi.
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