History of Chemistry, Volume 2 (of 2): From 1850 to 1910 — John Shaqi
History of Chemistry, Volume 2 (of 2): From 1850 to 1910Thorpe, T. E. (Thomas Edward)
History
History of Chemistry, Volume 2 (of 2): From 1850 to 1910
Thorpe, T. E. (Thomas Edward)
Chemistry -- History
By a special apparatus devised by
Lord Rayleigh, in which a mixture of air and oxygen is submitted to an
electric flame produced by a powerful, rapidly alternating current,
considerable quantities of argon were separated from the air. It has
also been found that by the use of metallic calcium or a mixture of
magnesium and lime, the atmospheric nitrogen is absorbed at a lower
temperature, and more rapidly than by magnesium alone.
Argon has been found to exist in the gases from springs and mineral
waters, notably in those of Bath, Cauterets, Wildbad, and Harrogate. It
has also been found in a meteorite, in the gas occluded in rock-salt,
and in the minerals _malacone_, _uraninite_, _brōggerite_, etc. No
animal or vegetable substance appears to contain it. It is present in
atmospheric air to the extent of about one per cent. by volume. It is
a colourless gas of an atomic weight of 39.9: one litre of it at the
standard temperature and pressure weighs 1.7815 grams. Experiments made
by the method of Kundt and Warburg—_i.e._, by determining the ratio
of the specific heats at constant pressure and constant volume by the
velocity of sound in the gas—prove that argon, like mercury gas, is
monatomic. This of itself indicates that argon is an element, since a
monatomic compound is a contradiction in terms. The calculations from
the experimental data presuppose that argon obeys the laws of Boyle and
Dalton, which was found on trial to be the case. By the application
of cold and pressure argon can be liquefied. The liquid boils at
-186°.1 and freezes at -187°.9. The spectrum of the gas is exceedingly
complicated, consisting of a great number of lines extending throughout
the visible portion and far into the extreme red and ultra-violet. The
colour of the light emitted on sparking the gas changes with increase
of temperature from a brilliant red to a bright blue—depending on the
intensity of the discharge. All attempts to induce argon to enter
into combination with other substances have failed. The methods of
its preparation show that it does not combine with oxygen, although
Troost and Ouvrard state that it unites with magnesium vapour. It forms
no compounds with hydrogen, chlorine, phosphorus, sulphur, sodium,
tellurium, etc. Even fluorine, probably the most generally active of
the chemical elements, shows no tendency to unite with it.
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