History of Chemistry, Volume 2 (of 2): From 1850 to 1910Thorpe, T. E. (Thomas Edward)
History
History of Chemistry, Volume 2 (of 2): From 1850 to 1910
Thorpe, T. E. (Thomas Edward)
Chemistry -- History
In 1888 Dr. Hillebrand, of the U.S. Geological Survey, in examining
a form of uraninite known as _cleveite_, so named from the late
Professor Cleve, found that on treatment with dilute sulphuric acid
it gave off considerable quantities of a gas which was assumed to
consist only of nitrogen, as it gave the spectroscopic reactions of
that element. To test whether this gas contained argon, Ramsay, in
1895, further examined it spectroscopically. After sparking it with
oxygen in the presence of caustic soda solution, in the way already
described, it gave no indications of argon. The main characteristic
of its spectrum was a bright yellow line, known as D3, not coincident
with that afforded by sodium, but identical in position with a line
detected in the chromosphere during the solar eclipse of 1868, which
line, on examination by Frankland and Lockyer, could not be ascribed
to any known element. For this supposed new element the name _helium_,
from ἥλιος, the sun, had been suggested. This was the first occasion
on which an element observed originally only in the sun was found to
occur also on the earth. The presence of the new element in the gas
from cleveite was subsequently confirmed by Langlet working in Cleve’s
laboratory.
[Illustration: SIR WILLIAM RAMSAY.]
Helium is a monatomic gas having the atomic weight 4. It is less
soluble in water than argon. Like argon, it shows no tendency to
enter into chemical union with any other substance. It has been found
in many minerals, particularly in those containing uranium and the
so-called rare earth metals. It also occurs among the gases issuing
from certain mineral springs, such as those of Bath and at Cauterets
in the Pyrenees, and also at Adano near Padua. The spectrum of helium
contains, in addition to the characteristic yellow line—by which its
presence had been recognised not only in the solar chromosphere, but
also in certain of the fixed stars—two lines in the red, and lines in
the green, blue, and violet. The character of the light emitted by
the spark-discharge is modified by the intensity of the discharge in
a manner similar to that of argon. It has been shown by Collie that
its spectrum is altered by the presence of mercury vapour. It is the
least refractive of all the gases. Helium was liquefied by Kammerlingh
Onnes in 1908. It forms a colourless liquid of sp. gr. 0.154, boiling
at -268.5; that is, 4°.5 above the absolute zero of temperature. Its
critical temperature is about 5° absolute, and its critical pressure
above 2¼ atmospheres.
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