History of Chemistry, Volume 2 (of 2): From 1850 to 1910Thorpe, T. E. (Thomas Edward)
History
History of Chemistry, Volume 2 (of 2): From 1850 to 1910
Thorpe, T. E. (Thomas Edward)
Chemistry -- History
Radium has an atomic weight of 226.5. It is regarded as a product
of the disintegration of uranium, the atomic weight of which is
238.5. It is believed to have been formed through an intermediate
product known as _ionium_, a radio-active element discovered by
Boltwood in the mineral _carnolite_. The atomic weight of ionium is
surmised to be about 230. Radium itself is supposed to form at least
eight disintegration products, the first of which is the so-called
_emanation_, discovered by Dorn in 1900, an inactive gas with an
atomic weight of about 180, giving a bright line spectrum, decomposing
into helium, liberating oxygen and hydrogen from water, and capable
of being condensed to a liquid and solidified at a low temperature.
Ramsay and Gray have determined its physical constants. The liquid
is phosphorescent and shines with a colour depending on the nature
of the glass of the vessel which contains it. The solid is also
phosphorescent, the colour varying with the temperature. It gives out
only α rays and in its disintegration, like radium, evolves heat. Its
position in the Periodic Table is probably above that of xenon. Other
products are known as _radio-lead_ and _polonium_. The latter substance
was identified by M. and Mme. Curie in 1898, and was the first of the
strongly radio-active substances to be recognised. In the periodic
system it seems to follow bismuth and to be a member of Group VI., with
a possible atomic weight of 210. Its spectroscopic characters have
recently been examined by Mme. Curie and Debierne, who have shown that
in its decay it evolves helium.
The rate of disintegration of radium is relatively slow; it has been
calculated that the time required for half of any given quantity of
radium to change completely into other products is about 2000 years.
Rutherford has calculated that in 26,000 years a kilogram of radium
would be reduced to one milligram of active substance, the remainder
having passed into degradation products.
In 1899 Debierne announced the existence of another radio-active
element contained in uranium minerals, which he termed _actinium_. This
is probably a disintegration product of uranium and identical with the
_emanium_ of Giesel. It occurs associated with the rare earths which
can be separated from the pitch-blende residues, and is eventually
found in the lanthanum salts. Nothing is known as to its atomic
weight or its chemical relationships. It undergoes change, and forms,
apparently, a gaseous emanation which rapidly disintegrates and can
be condensed to a liquid at a low temperature. Four other successive
products have been identified by the character of the radiation they
emit, their degradation constants, and the time required for one half
of any given quantity to disintegrate into other forms of matter.
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