History of Chemistry, Volume 2 (of 2): From 1850 to 1910Thorpe, T. E. (Thomas Edward)
History
History of Chemistry, Volume 2 (of 2): From 1850 to 1910
Thorpe, T. E. (Thomas Edward)
Chemistry -- History
_Thorium_ was shown to contain a radio-active element by Mme. Curie
and Schmidt, independently, in 1898. Whether thorium is itself
active is doubtful. The rate of disintegration of _radio-thorium_
is probably greater than that of uranium. It, too, seems to form a
gaseous emanation which can be condensed at the temperature of liquid
air and appears to be an inert gas of high molecular weight with the
characteristics of the argon family.
The type of radiation emitted by the several products has been
observed, and their constants of change and half-value periods
calculated; but little or nothing is known at present concerning their
atomic weights, spectroscopic or chemical characters.
CHAPTER IV
ATOMS AND MOLECULES: ATOMIC WEIGHTS AND EQUIVALENTS
It has already been pointed out that the discovery by Gay Lussac, and
independently by Dalton, that gases combine in simple proportions by
volume, and that the volume of the gaseous product, measured under
comparable conditions of temperature and pressure, stand in simple
relation to the volumes of the constituents, seemed to most of Dalton’s
contemporaries, but not to Dalton himself, to afford strong evidence
of the validity of his explanation of the essential nature of chemical
combination. It appeared obvious from the facts that there must exist
some simple relation between the densities, or specific gravities,
of the elementary gases and their atomic weights. When, however, the
principle underlying Gay Lussac’s law was extended so as to include
gases in general—both simple and compound—difficulties were met with
which were only satisfactorily cleared away during the latter half of
the nineteenth century. The first rational attempt to explain the
facts observed by Dalton and Gay Lussac, concerning the volumetric
relations of gases, was made in 1813 by Amedeo Avogadro by the
assumption that a given volume of all gases—simple or compound—contains
the same number of integral molecules; hence the relative weights
of these volumes represent the relative weights of the molecules.
According to Avogadro, in the case of the simple gases the integral
molecules are composed of a certain number of elementary molecules
of _the same kind_, whereas the integral molecules of compound gases
and vapours are made up of elementary molecules _of different kinds_.
The _elementary molecule_ of Avogadro is now termed the _atom_; his
_integral molecule_ we call simply a _molecule_. Similar conceptions
were published independently by Ampère in 1814. It follows from the
doctrine of Avogadro and Ampère that, as the number of integral
molecules is the same in equal volumes of all gases, these molecules
must be equidistant from each other, their mutual distances depending
upon pressure and temperature. This at once serves to explain the laws
of Boyle and Dalton that gases, no matter what their chemical nature,
behave identically, as regards change of volume, when compressed by
pressure or expanded by heat.
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