History of Chemistry, Volume 2 (of 2): From 1850 to 1910Thorpe, T. E. (Thomas Edward)
History
History of Chemistry, Volume 2 (of 2): From 1850 to 1910
Thorpe, T. E. (Thomas Edward)
Chemistry -- History
Our present tables of atomic weight bring, therefore, the values
for the several elements into harmony with the doctrine of Avogadro
and Ampère, with the law of Dulong and Petit, and with the facts of
isomorphism. The values are, in fact, in unison with all the criteria
which serve to indicate the atomic weights of the elements. As a
result, our present system of notation, which is, of course, based upon
these atomic weights, assigns formulæ to compounds which indicate their
true relative molecular weights and simplify the accurate expression
of their relationships and chemical transformations. One by one the
instances of anomalous vapour density, which were so many stumbling
blocks to the universal acceptance of a system based upon the law of
gaseous volumes, have been shown to be not only not inconsistent with
it, but actually so many corroborative proofs. Thus, in the case of
ammonium chloride, the observed vapour density of which was found to
be practically half its calculated value, it has been proved that
the vapour of this salt, when heated to the temperature at which the
observations were made, is mainly resolved into molecules of ammonia
and hydrogen chloride, which together occupy double the space of the
ammonium chloride molecule. Phosphorus pentachloride vapour, on being
sufficiently heated, is similarly more or less resolved into phosphorus
trichloride and chlorine.
Moreover, it has been found, by a more accurate study of the action
of heat upon the vapour of ammonium chloride and of phosphorus
pentachloride, that within certain narrow limits of temperature these
substances can actually exist as such in the gaseous state, and that
the density of their vapours does actually conform to that demanded
by theory. Moreover, phosphorus pentafluoride, the analogue of the
pentachloride, is gaseous at ordinary temperatures, and has a normal
density. It may be heated to a high temperature without showing any
sign of decomposition.
Limitations of space will not allow of a fuller explanation of the
apparent anomalies already alluded to. They have each in turn been
experimentally attacked and satisfactorily explained. No valid
exception is now known to the universal applicability of the principle.
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