History of Chemistry, Volume 2 (of 2): From 1850 to 1910Thorpe, T. E. (Thomas Edward)
History
History of Chemistry, Volume 2 (of 2): From 1850 to 1910
Thorpe, T. E. (Thomas Edward)
Chemistry -- History
To-day the chemical history of a substance, whether elementary or
compound, if vaporisable, is not complete until its vapour density is
known, since a knowledge of this constant affords the most certain
means of establishing the relative weight of its molecule. Accordingly
many chemists have endeavoured to simplify and render more convenient
the modes of determining vapour densities. Thanks to the efforts of
Hofmann and Victor Meyer, the processes associated with the names of
Dumas, Gay Lussac, Deville, and Troost, which have furnished us with
valuable information in the past, have now given way to comparatively
simple and rapid methods, which, although not necessarily more
accurate, furnish the required information with less expenditure of
time and trouble; that is to say, they serve to indicate which of
two, or more, presumed molecular weights is correct, and so enable
us to establish the molecular formula of the substance. The chemical
formula of a substance is a condensed expression of a number of facts
connected with its history. Thus the expression H2O—the chemical
formula for water—indicates that the substance is composed of hydrogen
and oxygen, in the proportion, using round numbers, of 2 parts by
weight of hydrogen and 16 parts by weight of oxygen; or, in other
words, of 2 atoms of hydrogen, each weighing 1, and 1 atom of oxygen
weighing 16. The formula, moreover, connotes the fact that when the
gases combine 2 volumes of hydrogen unite with 1 volume of oxygen to
form 2 volumes of water-vapour (steam). So, too, the formula HCl—which
represents hydrogen chloride—means that the substance is a compound of
1 atom of hydrogen weighing 1 united with 1 atom of chlorine weighing
35.5; it also denotes the fact that in the act of union 1 volume of
hydrogen combines with 1 volume of chlorine to form 2 volumes of
hydrogen chloride. Lastly, the formula NH3 signifies that the molecule
of ammonia is composed of 1 atom of nitrogen weighing 14, and 3 atoms
of hydrogen, each weighing 1; it further indicates that when ammonia
gas is resolved into its constituents, as it can be when sufficiently
heated, 2 volumes of ammonia gas are increased to 4 volumes of a
mixture made up of 1 volume of nitrogen and 3 volumes of hydrogen.
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