History of Chemistry, Volume 2 (of 2): From 1850 to 1910Thorpe, T. E. (Thomas Edward)
History
History of Chemistry, Volume 2 (of 2): From 1850 to 1910
Thorpe, T. E. (Thomas Edward)
Chemistry -- History
In short, all the formulæ are what are called _two-volume formulæ_;
that is, the relative molecular weights of the substances occupy
the same volume as two relative parts by weight of hydrogen. Hence
their vapour densities—referred to hydrogen as unity—are the halves
respectively of their molecular weights. Steam is 9 times, hydrogen
chloride 18.25 times, and ammonia 8.5 times heavier than hydrogen, when
measured under identical conditions of temperature and pressure. The
quantities expressed by the formulæ H2, H2O, HCl, NH3, occupy the same
volume. This is equally true of the quantities expressed by O2, N2,
Cl2, etc. These expressions signify that the molecules of the elements
of hydrogen, oxygen, nitrogen, and chlorine consist each of 2 atoms of
the respective substances: the molecule of water consists of 3 atoms—2
of hydrogen and 1 of oxygen; the molecule of hydrogen chloride of 2
atoms—1 of hydrogen and 1 of chlorine; whereas the molecule of ammonia
contains 4 atoms—1 atom of nitrogen and 3 atoms of hydrogen.
Certain of the elementary bodies are, as already stated, capable of
existing in different allotropic states. Thus there is a modification
of oxygen known as _ozone_. This substance has long been recognised as
being formed from air under the influence of the electric discharge. It
was the subject of study by Schönbein as far back as 1839; but that it
was a condensed form of oxygen and not a peroxide of hydrogen—as was at
one time surmised—was first established by Andrews and Tait. The degree
of its condensation was definitely ascertained by Soret by observing
its rate of diffusion, from which, on the basis of Graham’s law, its
density could be inferred. It was found to be 1½ times that of ordinary
oxygen. Hence, if the molecule of oxygen consists of 2 atoms, that of
ozone consists of 3 atoms. The chemical symbol of ozone is, therefore,
O3.
It has been found also that the molecule of sulphur, in the state of
solution, contains eight atoms. This complex molecule in the gaseous
state gradually breaks down as the temperature is increased, and at
temperatures above 850° contains, like its analogue oxygen, only
two atoms. The molecules of phosphorus and arsenic, in the gaseous
state, are each found to consist of four atoms. On the other hand, the
molecules of mercury, zinc, and cadmium each consist of only one atom.
As will be shown later, Kundt and Warburg established, in 1875, the
fact that mercury vapour is a monatomic gas, by determining the rate at
which sound is propagated through it. In the same way it was shown that
helium, argon, and its congeners are also, as already stated, monatomic
gases.
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