History of Chemistry, Volume 2 (of 2): From 1850 to 1910Thorpe, T. E. (Thomas Edward)
History
History of Chemistry, Volume 2 (of 2): From 1850 to 1910
Thorpe, T. E. (Thomas Edward)
Chemistry -- History
Lastly, it should be mentioned, the re-determination of the atomic
weights of the elements with the highest attainable precision and by
the most refined and most modern methods has for some years past been
a special feature of the work of the Harvard Laboratory, under the
direction of Theodore Richards; and some of the most trustworthy and
best established values we possess have been ascertained by him and
his pupils. Atomic weights are of such fundamental importance that the
various nations interested in the pursuit of chemistry have consented
to the establishment of an International Committee, which will take
cognisance of the work done from time to time in this department of
operative chemistry, examine and assess its value, and draw up an
annual report on the subject.
Despite the accumulated testimony of this work in relation to the
validity of the law of the conservation of mass, the sufficiency of the
evidence has now and again been impugned. This aspect of the matter
has within recent years been directly investigated by Landolt; and
as the result of a painstaking series of experiments, in which every
recognised source of error was removed or allowed for, it would appear
that there is absolutely no ground for the belief that there is any
dissipation of mass in the course of, or as the result of, a chemical
change.
CHAPTER V
THE MOLECULAR THEORY OF GASES
The more obvious physical phenomena of gases were, of course, well
known by the middle of the nineteenth century; and the so-called
gaseous laws—the laws of Boyle, Dalton, and Gay Lussac—were universally
accepted by chemists and physicists at that time as fundamental. That
the first two laws were only approximations to truth in a mathematical
sense was also well known; and the experimental labours of Regnault and
Magnus had not only established limits within which they were inexact,
but had, to some extent, indicated the cause of their departure from
the ideal condition. The hypothesis of Avogadro, as already stated,
was practically ignored at this period, or at least its value was
unappreciated until the time of Gerhardt and Laurent, and more
particularly Cannizzaro, who in 1858 pointed out its real meaning and
made it the keystone in the edifice of modern chemistry.
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