History of Chemistry, Volume 2 (of 2): From 1850 to 1910Thorpe, T. E. (Thomas Edward)
History
History of Chemistry, Volume 2 (of 2): From 1850 to 1910
Thorpe, T. E. (Thomas Edward)
Chemistry -- History
One of the most significant achievements of the last half-century has
been the demonstration that these gaseous laws are interdependent.
Their further study, and in particular the study of their variation
from exact mathematical expression, has led to a conception of the real
nature of a gas which not only comprehends and knits together these
laws, but affords a rational explanation of them. If the laws of Boyle
and Dalton concerning the relations between pressure, temperature, and
gaseous volume are, and must be from the very nature of the case, only
approximations, it follows that the same is equally true of the laws of
Gay Lussac and Avogadro, since these are dependent on the others. The
definite experimental proof that gases do not actually combine in the
precise ratios demanded by the law of Gay Lussac has been forthcoming
only during the last twenty years. It has been found that, instead
of oxygen and hydrogen combining in the exact ratio of one volume of
oxygen to two volumes of hydrogen to form water, as stated by Gay
Lussac, one volume of oxygen combines with, according to Scott, 2.00245
vols.; according to Leduc, 2.0024 vols.; according to Morley, 2.00268
vols. of hydrogen. What is true of the volume-ratios in which oxygen
and hydrogen are actually found to combine, under ordinary conditions,
is no doubt equally true of analogous instances, such as the union
of hydrogen and chlorine to form hydrogen chloride. It follows also
that the extent of the variation from the mathematical expression of
Gay Lussac’s law must get smaller and smaller as the combining gases
approach the condition of the ideal gas—as they do, for example, under
very low pressures. The precise degree of departure from Gay Lussac’s
law is therefore in a sense accidental, and is dependent upon the
conditions under which combination takes place.
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