Sir William Robert Grove, an English Judge and scientist, invented a cell in 1838 consisting of a platinum electrode in strong nitric acid in a porous earthenware jar. This jar was put in dilute sulphuric acid in a glass jar in which there was an amalgamated zinc plate for the other electrode. This had an open circuit voltage of about 1.9 volts. The porous jar was used to prevent the nitric acid from attacking the zinc. The nitric acid was used for the purpose of combining with the hydrogen gas set free by the action of the sulphuric acid on the zinc, and hence was the depolarizing agent. Hydrogen combining with nitric acid forms nitrous peroxide and water. Part of the nitrous peroxide is dissolved in the water, and the rest escapes as fumes which, however, are very suffocating. The chemical equations of this cell are as follows: In outer glass jar: Zn + H_{2}SO_{4} = ZnSO_{4} + H_{2} In inner porous jar: H_{2} + 2HNO_{3} = N_{2}O_{4} + 2H_{2}O An interesting thing about Grove’s cell is that it was planned in accordance with a theory. Grove knew that the electrical energy of the zinc-sulphuric acid cell came from the chemical affinity of the two reagents, and if the hydrogen gas set free could be combined with oxygen (to form water--H_{2}O), such chemical affinity should increase the strength of the cell. As the hydrogen gas appears at the other electrode, the oxidizing agent should surround that electrode. Nitric acid was known at that time as one of the most powerful oxidizing liquids, but as it attacks copper, he used platinum for the other electrode. Thus he not only overcame the difficulty of polarization by the hydrogen gas, but also increased the voltage of the cell by the added chemical action of the combination of hydrogen and oxygen. GROVE’S DEMONSTRATION OF INCANDESCENT LIGHTING In 1840 Grove made an experimental lamp by attaching the ends of a coil of platinum wire to copper wires, the lower parts of which were well varnished for insulation. The platinum wire was covered by a glass tumbler, the open end set in a glass dish partly filled with water. This prevented draughts of air from cooling the incandescent platinum, and the small amount of oxygen of the air in the tumbler reduced the amount of oxidization of the platinum that would otherwise occur. With current supplied by a large number of cells of his battery, he lighted the auditorium of the Royal Institution with these lamps during one of the lectures he gave. This lamp gave only a feeble light as there was danger of melting the platinum and platinum gives but little light unless operated close to its melting temperature. It also required a lot of current to operate it as the air tended to cool the incandescent platinum. The demonstration was only of scientific interest, the cost of current being much too great (estimated at several hundred dollars a kilowatt hour) to make it commercial. GRENET BATTERY