It was discovered that chromic anhydride gives up oxygen easier than
nitric acid and consequently if used would give a higher voltage than
Grove’s nitric acid battery. It also has the advantage of a lesser
tendency to attack zinc directly if it happens to come in contact with
it. Grenet developed a cell having a liquid consisting of a mixture of
potassium bichromate (K_{2}Cr_{2}O_{7}) and sulphuric acid. A porous
cell was therefore not used to keep the two liquids apart. This had the
advantage of reducing the internal resistance. The chemical reaction
was:
K_{2}Cr_{2}O_{7} (potassium bichromate) + 7H_{2}SO_{4} (sulphuric
acid) + 3Zn (zinc) = 3ZnSO_{4} (zinc sulphate) + K_{2}SO_{4}
(potassium sulphate) + Cr_{2} (SO_{4})_{3} (chromium sulphate)
+ 7H_{2}O (water).
In order to prevent the useless consumption of zinc on open circuit,
the zinc was attached to a sliding rod and could be drawn up into the
neck of the bottle-shaped jar containing the liquid.
[Illustration: GROVE’S INCANDESCENT LAMP, 1840.
Grove made an experimental lamp, using platinum for the burner which
was protected from draughts of air by a glass tumbler.]
DE MOLEYNS’ INCANDESCENT LAMP
Frederick De Moleyns, an Englishman, has the honor of having obtained
the first patent on an incandescent lamp. This was in 1841 and his
lamp was quite novel. It consisted of a spherical glass globe, in the
upper part of which was a tube containing powdered charcoal. This tube
was open at the bottom inside the globe and through it ran a platinum
wire, the end below the tube being coiled. Another platinum wire coiled
at its upper end came up through the lower part of the globe but did
not quite touch the other platinum coil. The powdered charcoal filled
the two coils of platinum wire and bridged the gap between. Current
passing through this charcoal bridge heated it to incandescence. The
air in the globe having been removed as far as was possible with the
hand air pumps then available, the charcoal did not immediately burn
up, the small amount consumed being replaced by the supply in the
tube. The idea was ingenious but the lamp was impractical as the globe
rapidly blackened from the evaporation of the incandescent charcoal.
[Illustration: DE MOLEYNS’ INCANDESCENT LAMP, 1841.
This consisted of two coils of platinum wire containing powdered
charcoal operating in a vacuum. It is only of interest as the first
incandescent lamp on which a patent (British) was granted.]
EARLY DEVELOPMENTS OF THE ARC LAMP
It had been found that most of the light of the arc came from the
tip of the positive electrode, and that the charcoal electrodes were
rapidly consumed, the positive electrode about twice as fast as the
negative. Mechanisms were designed to take care of this, together with
devices to start the arc by allowing the electrodes to touch each other
and then pulling them apart the proper distance. This distance varied
from one-eighth to three-quarters of an inch.
Public-domain text, read in full here on John Shaqi.
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