As already stated, two Gay-Lussac towers are usually connected together,
or where there are several lead-chamber systems there is, apart from the
Gay-Lussac attached to each, a central Gay-Lussac in addition, common
to the whole series. The introduction of several Gay-Lussac towers
has the advantage of preventing loss of the nitrous fumes as much as
possible—mainly on economical grounds, as nitric acid is expensive. But
this arrangement is at the same time advantageous on hygienic grounds, as
escape of poisonous gases containing nitrous fumes, &c., is effectually
avoided. The acids are driven to the top of the towers by compressed air.
The whole system—chambers and towers—is connected by means of wide lead
conduits. Frequently, for the purpose of quickening the chamber process
(by increasing the number of condensing surfaces) Lunge-Rohrmann plate
towers are inserted in the system—tall towers lined with lead in which
square perforated plates are hung horizontally, and down which diluted
sulphuric acid trickles.
To increase the draught in the whole system a chimney is usual at
the end, and, in addition, a fan of hard lead or earthenware may be
introduced in front of the first chamber or between the two Gay-Lussac
towers. Maintenance of a constant uniform draught is not only necessary
for technical reasons, but has hygienic interest, since escape of
injurious gases is avoided (see also Part III).
The chamber acid (of 110°-120° Tw. = 63-70 %) and the stronger Glover
acid (of 136°-144° Tw. = 75-82 %) contain impurities. In order to obtain
for certain purposes pure strong acid the chamber acid is purified and
concentrated. The impurities are notably arsenious and nitrous acids
(Glover acid is N free), lead, copper, and iron. Concentration (apart
from that to Glover acid in the Glover tower) is effected by evaporation
in lead pans to 140° Tw. and finally in glass balloons or platinum stills
to 168° Tw. (= 97 %). The lead pans are generally heated by utilising the
waste heat from the furnaces or by steam coils in the acid itself, or
even by direct firing.
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