Production of sulphuric acid by the _contact method_ depends on the fact
that a mixture of sulphur dioxide and excess of oxygen (air) combines
to form sulphur trioxide at a moderate heat in presence of a contact
substance such as platinised asbestos or oxide of iron. The sulphur
dioxide must be carefully cleaned and dried, and with the excess of air
is passed through the contact substance. If asbestos carrying a small
percentage of finely divided platinum is the contact substance, it is
generally used in the form of pipes; oxide of iron (the residue of
pyrites), if used, is charged into a furnace. Cooling by a coil of pipes
and condensation in washing towers supplied with concentrated sulphuric
acid always forms a part of the process. A fan draws the gases from the
roasting furnaces and drives them through the system. The end product
is a fuming sulphuric acid containing 20-30 per cent. SO₃. From this by
distillation a concentrated acid and a pure anhydride are obtained. From
a health point of view it is of importance to know that all sulphuric
acid derived from this anhydride is pure and free from arsenic.
The most important _uses_ of sulphuric acid are the following: as chamber
acid (110°-120° Tw.) in the superphosphate, ammonium sulphate, and alum
industries; as Glover acid (140°-150° Tw.) in the Leblanc process, i.e.
saltcake and manufacture of hydrochloric acid, and to etch metals; as
sulphuric acid of 168° Tw. in colour and explosives manufacture (nitric
acid, nitro-benzene, nitro-glycerine, gun-cotton, &c.); as concentrated
sulphuric acid and anhydride for the production of organic sulphonic
acids (for the alizarin and naphthol industry) and in the refining of
petroleum and other oils. Completely de-arsenicated sulphuric acid
is used in making starch, sugar, pharmaceutical preparations, and in
electrical accumulator manufacture.
EFFECTS ON HEALTH.—The health of sulphuric acid workers cannot in general
be described as unfavourable.
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