Similar accidents have occurred in cleaning out the Gay-Lussac towers.
Such poisonings have repeatedly occurred in Germany. Fatal poisoning is
recorded in the report of the Union of Chemical Industry, in the emptying
and cleaning of a Gay-Lussac tower despite careful precautions. The
tower, filled with coke, had been previously well washed with water, and
during the operation of emptying, air had been constantly blown through
by means of a Körting’s injector. The affected worker had been in the
tower about an hour; two hours later symptoms of poisoning set in which
proved fatal in an hour despite immediate medical attention. As such
accidents kept on recurring, the Union of Chemical Industry drew up
special precautions to be adopted in the emptying of these towers, which
are printed in Part III.
Naturally, in all these cases it is difficult to say exactly which of the
acid gases arising in the production of sulphuric acid was responsible
for the poisoning. In the fatal cases cited, probably nitrous fumes
played the more important part.
Poisoning has occurred in the transport of sulphuric acid. In some of
the cases, at all events, gaseous impurities, especially arseniuretted
hydrogen, were present.
Thus, in the reports of the German Union of Chemical Industry for the
year 1901, a worker succumbed through inhalation of poisonous gases in
cleaning out a tank waggon for the transport of sulphuric acid. The tank
was cleaned of the adhering mud, as had been the custom for years, by a
man who climbed into it. No injurious effects had been noted previously
at the work, and no further precautions were taken than that one worker
relieved another at short intervals, and the work was carried on under
supervision. On the occasion in question, however, there was an unusually
large quantity of deposit, although the quality of the sulphuric acid was
the same, and work had to be continued longer. The worker who remained
longest in the tank became ill on his way home and died in hospital
the following day; the other workers were only slightly affected. The
sulphuric acid used by the firm in question immediately before the
accident came from a newly built factory in which anhydrous sulphuric
acid had been prepared by a special process. The acid was Glover acid,
and it is possible that selenium and arsenic compounds were present
in the residues. Arseniuretted hydrogen might have been generated in
digging up the mud. Two similar fatalities are described in the report of
the same Union for the year 1905. They happened similarly in cleaning out
a sulphuric acid tank waggon, and in them the arsenic in the acid was the
cause. Preliminary swilling out with water diluted the remainder of the
sulphuric acid, but, nevertheless, it acted on the iron of the container.
Generation of hydrogen gas is the condition for the reduction of the
arsenious acid present in sulphuric acid with formation of arseniuretted
hydrogen. In portions of the viscera arsenic was found.
Public-domain text, read in full here on John Shaqi.
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