In comparison with chemical workers they have, it is said, relatively
the lowest morbidity. Although in this industrial occupation no
special factors are at work which injure in general the health of the
workers, there is a characteristic effect, without doubt due to the
occupation—namely, disease of the respiratory organs. Leymann’s figures
are sufficiently large to show that the number of cases of diseases
of the respiratory organs is decidedly greater in the sulphuric acid
industry than among other chemical workers. He attributes this to the
irritating and corrosive effect of sulphur dioxide and sulphuric acid
vapour on the mucous membrane of the respiratory tract, as inhalation
of these gases can never be quite avoided, because the draught in the
furnace and chamber system varies, and the working is not always uniform.
Strongly irritating vapours escape again in making a high percentage
acid in platinum vessels, which in consequence are difficult to keep
air-tight. Of greater importance than these injurious effects from
frequent inhalation of small quantities of acid vapours, or employment
in workrooms in which the air is slightly charged with acid, is the
accidental sudden inhalation of large quantities of acid gases, which may
arise in the manufacture, especially by careless attendance. Formerly
this was common in charging the roasting furnaces when the draught in the
furnace, on addition of the pyrites, was not strengthened at the same
time. This can be easily avoided by artificial regulation of the draught.
Accidents through inhalation of acid gases occur further when entering
the lead chambers or acid tanks, and in emptying the towers. Heinzerling
relates several cases taken from factory inspectors’ reports. Thus, in a
sulphuric acid factory the deposit (lead oxysulphate) which had collected
on the floor of a chamber was being removed: to effect this the lead
chambers were opened at the side. Two of the workers, who had probably
been exposed too long to the acid vapours evolved in stirring up the
deposit, died a short time after they had finished the work. A similar
fatality occurred in cleaning out a nitro-sulphuric acid tank, the
required neutralisation of the acid by lime before entering having been
omitted. Of the two workers who entered, one died the next day; the other
remained unaffected. The deceased had, as the post mortem showed, already
suffered previously from pleurisy. A fatality from breathing nitrous
fumes is described fully in the report of the Union of Chemical Industry
for the year 1905. The worker was engaged with two others in fixing a fan
to a lead chamber; the workers omitted to wait for the arrival of the
foreman who was to have supervised the operation. Although the men used
moist sponges as respirators, one of them inhaled nitrous fumes escaping
from the chamber in such quantity that he died the following day.
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