The Austrian Gas Regulations (of July 18, 1906) contain general
provisions as to impermeability and security of the gas pipes and the
precautions to be observed in their installation. Special directions
follow as to main flues, material, dimensions, branches, and connections,
valve arrangements, testing of the pipes against leakage, directions
for discovering leaks, and other defects; also the nature of the branch
pipes (dimensions and material), valves, cocks, syphons, water seals, and
pressure gauges. In addition there are directions as to testing pipes and
how to deal with escape of gas, freezing of pipes, and other mishaps.
Ammonia
(See also pp. 90-3 and 175)
In the production of ammonia and ammonium salts (ammonium sulphate)
combination of the ammoniacal vapour with the sulphuric acid is
accompanied with the formation of volatile dangerous gases containing
sulphuretted hydrogen and cyanogen compounds, which produce marked
oppression and sometimes endanger the health of the workers. Drawing-off
these fumes into the furnace (practised sometimes in small industries)
is not advisable, as the sulphuretted hydrogen is burnt to sulphur
dioxide; if it is burnt absorption of the sulphur dioxide should follow,
or working it up into sulphuric acid (Leymann). Often these gases are
freed from cyanogen compounds and sulphuretted hydrogen by means of gas
purifying materials, such as are used in gas works. The whole apparatus
must be impervious. Where liquids containing ammonia are used exhaust
ventilation is necessary.
Cyanogen, Cyanogen Compounds
(See also pp. 93-5 and 195-7)
Processes in which cyanogen gas can develop, require to be done under a
powerful exhaust draught.
In the production of cyanogen compounds possibility of the escape of
hydrocyanic acid (prussic acid) has to be borne in mind. Such escape is
possible in its production from raw animal products.
The most careful cleanliness and observance of general measures for
personal hygiene are necessary in factories in which cyanogen compounds
are manufactured or handled. In crushing cyanide of potassium the workers
should wear indiarubber gloves and respirators. The products should be
stored in closed vessels in dry store rooms set apart for the purpose.
Modern cyanide of potassium factories which work up molasses, from which
the sugar has been removed, and also residuary distillery liquors, so
far conform with hygienic requirements that all the apparatus is under
negative pressure, so that poisonous gases cannot escape into the
workrooms.
Coal Tar, Tar Products
(See also pp. 96-119)
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