In tar distillation and in the _production_ and _use_ of _benzene_
industrial poisoning frequently occurs. Many cases are recorded, but in
several the immediate exciting cause is doubtful, and consequently it is
often difficult to classify the cases.
Most frequently the manufacture and use of benzene come in question.
Besides this, in tar distillation poisoning may be caused by other
substances, such as sulphuretted hydrogen gas, carbonic oxide gas, &c. In
the production of antipyrin, aspirin, &c., and in the preparation and use
of anthracene injury to health is recognised.
From the list of recognised cases of these forms of poisoning the most
characteristic are chosen from the recent literature on the subject.
The Prussian factory inspectors’ reports for 1904 describe the following:
In cleaning out a tar still two workers were killed by inhalation of gas.
The nature of the gas was not ascertained. But what probably happened was
that the cock on the foul gas pipe collecting the gases from the stills
leaked and allowed fumes to pass over from one still to another.
A foreman and worker were rendered unconscious on entering a receiver
for heavy oil for cleaning purposes. On treatment with oxygen gas they
speedily recovered.
_Industrial benzene poisoning_ is especially frequent now in view of the
increasing use to which it is put. Several cases have proved fatal.
A worker, for instance, forgot to open the cock for the water to cool the
condenser, so that some of the benzene vapour remained uncondensed. The
case proved fatal.
The Report of the Union of Chemical Industry for 1905 stated that a
worker on night duty, whose duty it was to regulate the introduction
of steam and the cooling of the benzol plant, was found lying dead in
front of the building. Inquiry showed that he had not opened the valve
for running the distillate into the appropriate receiver. Eight thousand
litres overflowed.
In an indiarubber extracting factory a worker was rendered unconscious
while inspecting a benzol still; before entering he had omitted to
observe the instructions to drive steam through and have a mate on watch
at the manhole. Two other workmen were similarly affected who went to the
rescue without adoption of precautions. Only one survived.
In a further accident (already mentioned under ‘Coke Furnaces’) two
workmen were killed. In the factory in question the thick tar from the
coke ovens was being distilled under slight pressure. The air pumps,
however, were out of order, and temporary use was being made of Körting’s
injectors, whereby the steam and tar constituents were cooled and led
into the drain in front of the closet, near to which was a ventilating
shaft. Probably, in addition to benzene and its homologues, sulphuretted
hydrogen and cyanogen compounds were present in the poisonous gases.
In cleaning out a benzene extracting apparatus a workman was killed by
the stagnant fumes in it.
Public-domain text, read in full here on John Shaqi.
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