Lead Smelting and Refining, With Some Notes on Lead Mining
Science
Lead Smelting and Refining, With Some Notes on Lead Mining
Lead -- Metallurgy; Lead mines and mining
The reactions above described are as outlined in the original
American patent specification. Irrespective of their accuracy,
the Carmichael-Bradford process is obviously quite similar to the
Huntington-Heberlein, and doubtless owes its origin to the latter. The
difference between them is that in the Huntington-Heberlein process
the ore is first partially roasted with addition of lime, and is then
converted in a special vessel. In the Carmichael-Bradford process
the ore is mixed with gypsum and is then converted directly. The
greatest claim for originality in the Carmichael-Bradford process
may be considered to lie in it as a method of desulphurizing gypsum,
inasmuch as not only is the sulphur of the ore expelled, but also a
part of the sulphur of the gypsum; and the sulphur is driven off as a
gas of sufficiently high tenor of sulphur dioxide to enable sulphuric
acid to be made from it economically. Up to the present time the
Carmichael-Bradford process has been put into practical use only at
Broken Hill, N. S. W.
The Broken Hill Proprietary Company first conducted a series of tests
in a converter capable of treating a charge of 20 cwt. These tests were
made at the smelting works at Port Pirie. Exhaustive experiments made
on various classes of ores satisfactorily proved the general efficacy
of the process. The following ores were tried in these preliminary
experiments, viz.:
First-grade concentrate containing: Pb, 60 per cent.; Zn, 10 per cent.;
S, 16 per cent.; Ag, 30 oz.
Second-grade concentrate containing: Pb, 45 per cent.; Zn, 12.5 per
cent.; S, 14.5 per cent.; Ag, 22 oz.
Slime containing: Pb, 21 per cent.; Zn, 17 per cent.; S, 13 per cent.;
Ag, 18 oz.
Lead-copper matte containing: Fe, 42 per cent.; Pb, 17 per cent.; Zn,
13.3 per cent.; Cu, 2.4 per cent.; S, 23 per cent.; Ag, 25 oz.
Other mattes, of varying composition up to 45 per cent. Pb and 100 oz.
Ag, were also tried.
The results from these preliminary tests were so gratifying that a
further set of tests was made on lead-zinc slime, with a view of
ascertaining whether any volatilization losses occurred during the
desulphurization. This particular material was chosen because of its
accumulation in large proportions at the mine, and the unsatisfactory
result of the heap roasting which has recently been practised. The
heap roasting, although affording a product containing only 7 per cent.
S, which is delivered in lump form and therefore quite suitable for
smelting, resulted in a high loss of metal by volatilization (17 per
cent. Pb, 5 per cent. Ag).
The result of nine charges of the slime treated by the
Carmichael-Bradford process was as follows:
Public-domain text, read in full here on John Shaqi.
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