Lead Smelting and Refining, With Some Notes on Lead Mining
Science
Lead Smelting and Refining, With Some Notes on Lead Mining
Lead -- Metallurgy; Lead mines and mining
The converter charge consisted of 100 parts of the concentrate and
25 parts of raw gypsum, crushed to pass a 1 in. hole and retained
by a 0.25 in. hole, the material finer than 0.25 in. (which amounted
to 5 per cent. of the total) being returned to the pug-mill. After
desulphurization in the converter, the product assayed as follows:
48.9 per cent. lead; 1.80 per cent. iron; 0.80 per cent. manganese;
7.87 per cent. zinc; 3.90 per cent. sulphur; 1.02 per cent. alumina;
5.80 per cent. lime; 21.75 per cent. insoluble residue; 8.16 per cent.
undetermined (oxygen as oxides, sulphates, etc.); total, 100 per cent.
Its silver content was 22 oz. per ton. The desulphurized ore weighed
10 per cent. more than the raw concentrate. During this run 34 tons of
acid were made.
A trial was then made on 75 tons of slime of the following composition:
18.0 per cent. lead; 16.6 per cent. zinc; 6.0 per cent. iron; 2.5 per
cent. manganese; 3.2 per cent. alumina; 2.1 per cent. lime; 38.5 per
cent. insoluble residue; total, 100 per cent. Its silver content was
19.2 oz. per ton.
The converter charge in this case consisted of 100 parts of raw slime
and 30 parts of gypsum. The converted material assayed as follows:
16.1 per cent. lead; 14.0 per cent. zinc; 3.6 per cent. sulphur; 5.42
per cent. iron; 2.25 per cent. manganese; 4.10 per cent. alumina; 8.60
per cent. lime; 39.80 per cent. insoluble residue; 6.13 per cent.
undetermined (oxygen, etc.); total, 100 per cent.; and silver, 17.5
oz. per ton. The increase in weight of desulphurized ore over that
of the raw ore was 11 per cent. During this run 22 tons of acid were
manufactured.
The analysis of the gypsum used in each of the above tests (at Broken
Hill) was as follows: 76.1 per cent. CaSO₄, 2H₂O; 0.5 per cent.
Fe₂O₃; 4.5 per cent. Al₂O₃; 18.9 per cent. insoluble
residue.
The plant was then put into continuous operation on a mixture of three
parts slime and one of concentrate, desulphurizing down to 4 per cent.
S, and supplying 20 tons of acid per week, and additions were made to
the plant as soon as possible. The acid made at Broken Hill has been
used in connection with the Delprat process for the concentration of
the zinc tailing. At Port Pirie, works are being erected with capacity
for desulphurization of about 35,000 tons per annum, with an acid
output of 10,000 tons. This acid is to be utilized for the acidulation
of phosphate rock.
[Illustration: FIG. 15.—Details of Converters.]
The cost of desulphurization of a ton of galena concentrate by the
Carmichael-Bradford process, based on labor at $1.80 per 8 hours,
gypsum at $2.40 per 2240 lb., and coal at $8.40 per 2240 lb., is
estimated as follows:
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