Lead Smelting and Refining, With Some Notes on Lead Mining
Science
Lead Smelting and Refining, With Some Notes on Lead Mining
Lead -- Metallurgy; Lead mines and mining
In the Huntington-Heberlein process, the ore is mixed with suitable
proportions of limestone and silica (or quartzose ore) and is then
partially roasted, say to reduction of the sulphur to one half. The
roasting is done at a comparatively low temperature, and the loss of
metals is consequently small. The roasted ore is dampened and allowed
to cool. It is then charged into a hemispherical cast-iron pot, with
a movable hood which covers the top and conveys off the gases. There
is a perforated grate in the bottom of the pot, on which the ore
rests, and air is introduced through a pipe entering the bottom of the
pot, under the grate. A small quantity of red-hot calcines from the
roasting furnaces is thrown on the grate to start the reaction; a layer
of cold, semi-roasted ore is put upon it, the air blast is turned on
and reaction begins, which manifests itself by the copious evolution
of sulphur fumes. These consist chiefly of sulphur dioxide, but they
contain more or less trioxide, which is evident from the solution of
copperas that trickles from the hoods and iron smoke-pipes, wherein the
moisture condenses. As the reaction progresses, and the heat creeps
up, more ore is introduced, layer by layer, until the pot is full.
Care is taken by the operator to compel the air to pass evenly and
gently through the charge, wherefore he is watchful to close blow-holes
which develop in it. At the end of the operation, which may last from
four to eighteen hours, the ore becomes red-hot at the top. The hood
is then pushed up, and the pot is turned on its trunnions, by means
of a hand-operated wheel and worm-gear, until the charge slides out,
which it does as a solid, semi-fused cake. The pot is then turned back
into position. Its design is such that the air-pipe makes automatic
connection, a flanged pipe cast with the pot settling upon a similarly
flanged pipe communicating with the main, a suitable gasket serving
to make a tight joint. The pots are set at an elevation of about 12
ft. above the ground, so that when the charge slides out the drop will
break it up to some extent, and it is moreover caused to fall on a
wedge, or similar contrivance, to assist the breakage. After cooling it
is further broken up to furnace size by wedging and sledging; the lumps
are forked out, and the fines screened and returned to a subsequent
charge for completion of their desulphurization.
Public-domain text, read in full here on John Shaqi.
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