Lead Smelting and Refining, With Some Notes on Lead Mining
Science
Lead Smelting and Refining, With Some Notes on Lead Mining
Lead -- Metallurgy; Lead mines and mining
At the present time there are two views. In one, formulated most
explicitly by Professor Borchers, there is formed in this process a
plumbate of calcium, which is an active oxidizing agent. A formation of
this substance was also described by Carmichael in his original patent,
but he considered it to be the final product, not the active oxidizing
agent.
In the other view, the lime, or limestone, serves merely as a diluent
of the charge, enabling the air to obtain access to the particles of
galena, without liquefaction of the latter. The oxidation of the lead
sulphide is therefore effected chiefly by the air, and the process
is analogous to what takes place in the bessemer converter or in the
Germot process of smelting, or perhaps more closely to what might
happen in an ordinary roasting furnace, provided with a porous hearth,
through which the air supply would be introduced. Roasting furnaces of
that design have been proposed, and in fact such a construction is now
being tested for blende roasting in Kansas.
Up to the present time, the evidence is surely too incomplete to enable
a definite conclusion to be reached. Some facts may, however, be stated.
There is clearly reaction to a certain extent between lead sulphide
and lead sulphate, as in the reverberatory smelting furnace, because
prills of metallic lead are to be observed in the lime-roasted charge.
There is a formation of sulphuric acid in the lime-roasting, upon the
oxidizing effect of which Savelsberg lays considerable stress, since
its action is to be observed on the iron work in which it condenses.
Calcium sulphate, which is present in all of the processes, being
specifically added in the Carmichael-Bradford, evidently plays an
important chemical part, because not only is the sulphur trioxide
expelled from the artificial gypsum, but also it is to a certain
extent expelled from the natural gypsum, which is added in the
Carmichael-Bradford process; in other words, more sulphur is given off
by the charge than is contained by the metallic sulphides alone.
Further evidence that lime does indeed play a chemical part in the
reaction is presented by the phenomena of lime-roasting in clay dishes
in the assay muffle, wherein the air is certainly not blown through the
charge, which is simply exposed to superficial oxidation as in ordinary
roasting.
The desulphurized charge dropped from the pot is certainly at much
below the temperature of fusion, even in the interior, but we have no
evidence of the precise temperature condition during the process itself.
Pyrite and even zinc blende in the ore are completely oxidized. This,
at least, indicates intense atmospheric action.
Public-domain text, read in full here on John Shaqi.
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